Heravi Majid M, Zadsirjan Vahideh, Kouhestanian Elham, AlimadadiJani Behnoush
Department of Chemistry, School of Science, Alzahra University, POBox 1993891176, Vanak, Tehran, Iran.
Chem Rec. 2020 Apr;20(4):273-331. doi: 10.1002/tcr.201900018. Epub 2019 Aug 19.
One of the most important name reactions in organic chemistry, is the Diels-Alder cycloaddition reaction. It is a chemical reaction between a conjugated diene and a substituted alkene, commonly termed the dienophile to construct a substituted cyclohexene derivative. It is the stereotypical example of a pericyclic reaction with a concerted mechanism. In synthesis, the use of electricity instead of stoichiometric amounts of oxidant or reducing agents is definitely appealing for economic, ecological and selective, reasons. In this review, we try to underscore the combination of the electrosynthesis with Diels-Alder cycloaddition reaction to establish of a powerful synthetic tool which may encourage synthetic organic chemists to use it in the future.
有机化学中最重要的命名反应之一是狄尔斯-阿尔德环加成反应。它是共轭二烯与取代烯烃（通常称为亲双烯体）之间的化学反应，用于构建取代的环己烯衍生物。它是具有协同机理的周环反应的典型例子。在合成中，出于经济、生态和选择性的原因，使用电而不是化学计量的氧化剂或还原剂肯定很有吸引力。在本综述中，我们试图强调电合成与狄尔斯-阿尔德环加成反应的结合，以建立一种强大的合成工具，这可能会鼓励有机合成化学家在未来使用它。
