具有强烈圆偏振发光的手性双钉合邻菲咯啉衍生物
Chiral double stapled o-OPEs with intense circularly polarized luminescence.
作者信息
Reine Pablo, Campaña Araceli G, Alvarez de Cienfuegos Luis, Blanco Victor, Abbate Sergio, Mota Antonio J, Longhi Giovanna, Miguel Delia, Cuerva Juan M
机构信息
Department of Organic Chemistry, Faculty of Science, Universidad de Granada (UGR), Unidad de Excelencia de Química (UEQ), E-18071 Granada, Spain.
Department of Molecular and Translational Medicine, Università di Brescia, Brescia, Italy.
出版信息
Chem Commun (Camb). 2019 Sep 16;55(72):10685-10688. doi: 10.1039/c9cc04885e. Epub 2019 Aug 21.
Intrinsically chiral double stapled ortho-oligo phenylene ethynylenes (o-OPEs) 1 show g values up to 5.5 × 10, the second highest value ever observed for a simple organic molecule (SOM). DFT calculations of molecular spectra and properties encompassing electric and magnetic dipole transition moments account for these observations.
具有固有手性的双钉联邻亚苯基乙炔（o-OPEs）1的g值高达5.5×10，这是简单有机分子（SOM）观测到的第二高值。包含电偶极和磁偶极跃迁矩的分子光谱和性质的密度泛函理论计算解释了这些观测结果。
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