Monitoring, Planning and Evaluation Directorate, Ghana Standards Authority, P.O Box MB, 245, Accra, Ghana.
Institute for Environment and Sanitation Studies (IESS), University of Ghana, Legon, P. O. Box LG, 209, Ghana.
Environ Monit Assess. 2019 Aug 23;191(9):588. doi: 10.1007/s10661-019-7745-0.
This study evaluates the extent to which humans may be exposed to health risk from heavy metals in surface soils of public parks in Southern Ghana during outdoor activities. The study investigated surface soils of 56 public parks from seven metropolitan cities in Southern Ghana. Heavy metals (Cd, Cr, Cu, Hg, Mn, Ni, Pb, and Zn) were determined using microwave-assisted HNO-HF acid digestion and atomic absorption spectroscopy with flame, graphite furnace, and cold vapor options. All parks studied registered the presence of heavy metals with mean concentrations following the order: Mn > Zn > Cr > Pb > Cu > Ni > Cd > Hg. Whereas the mean concentrations of Zn (221.92 mg/kg) and Cr (107.01 mg/kg) respectively exceeded the Canadian (200 mg/kg; 64 mg/kg) and the EU (100-200 mg/kg; 50-100 mg/kg) standards, the ranges of Cu (14.27-138.85 mg/kg) and Pb (6.46-628.31 mg/kg) also exceeded their EU range of 50-100 mg/kg. The results indicated that there was no immediate risk to Ni and Hg on the public parks studied; however, Pb, Cd, Zn, Cu, and Cr may pose some adverse effects as they exceed their respective guideline limits in soil. The ranges of non-carcinogenic risk for adults and children were 0.0186-0.0787 and 0.0197-0.0850 respectively while the corresponding ranges for carcinogenic risks were 3.75 × 10-1.28 × 10 and 4.17 × 10-1.31 × 10. Even though risk assessment suggested low and acceptable health risk levels to patrons, there is the need for close monitoring since Pb, Cd, Zn, Cu, and Cr have shown tendency of accumulating beyond acceptable limit.
本研究评估了人类在加纳南部的 56 个公共公园进行户外活动时,通过接触表层土壤而暴露在重金属污染下的健康风险程度。这些公园分布在加纳南部的 7 个大城市中。通过微波辅助 HNO3-HF 酸消解和火焰原子吸收光谱法、石墨炉原子吸收光谱法和冷蒸气原子吸收光谱法测定了土壤中的重金属(Cd、Cr、Cu、Hg、Mn、Ni、Pb 和 Zn)。研究发现所有公园都存在重金属,其平均浓度的顺序为:Mn>Zn>Cr>Pb>Cu>Ni>Cd>Hg。虽然 Zn(221.92mg/kg)和 Cr(107.01mg/kg)的平均浓度分别超过了加拿大(200mg/kg;64mg/kg)和欧盟(100-200mg/kg;50-100mg/kg)的标准,但 Cu(14.27-138.85mg/kg)和 Pb(6.46-628.31mg/kg)的浓度范围也超过了欧盟的 50-100mg/kg 的范围。结果表明,在所研究的公共公园中,Ni 和 Hg 没有直接的风险;然而,Pb、Cd、Zn、Cu 和 Cr 可能会造成一些不利影响,因为它们的浓度超过了土壤中的指导限值。成人和儿童的非致癌风险范围分别为 0.0186-0.0787 和 0.0197-0.0850,而相应的致癌风险范围分别为 3.75×10-1-1.28×10-1 和 4.17×10-1-1.31×10-1。尽管风险评估表明,顾客面临的健康风险水平较低且可以接受,但由于 Pb、Cd、Zn、Cu 和 Cr 有超过可接受限值的积累趋势,因此仍需要密切监测。