一种整合的 Re(i) 光催化剂/敏化剂，可通过还原 CO 来激活甲酸的形成。
An integrated Re(i) photocatalyst/sensitizer that activates the formation of formic acid from reduction of CO.
机构信息
Department of Chemistry and Biomolecular Sciences, Centre for Catalysis Research and Innovation University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5, Canada.
出版信息
Chem Commun (Camb). 2019 Sep 21;55(74):11041-11044. doi: 10.1039/c9cc03943k. Epub 2019 Aug 27.
The complex cis-[Re(bpy)(CO)]OTf (1OTf) is an integrated photosensitizer/catalyst for the selective visible light promoted photocatalytic reduction of CO. The formation of formic acid is unique among this class of Re catalysts, which yield CO as the selective product. A supplemental photosensitizer, Ru(bpy), considerably enhanced the performance of this catalyst.
顺式-[Re(bpy)(CO)]OTf（1OTf）是一种集成的光催化剂/催化剂，可用于选择性可见光促进的 CO 光催化还原。在这类 Re 催化剂中，甲酸的形成是独特的，它们生成 CO 作为选择性产物。一种辅助光催化剂 Ru(bpy) 显著提高了该催化剂的性能。
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