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用于高性能超级电容器应用的不同形貌SnS纳米结构的简便合成

Facile Synthesis of SnS Nanostructures with Different Morphologies for High-Performance Supercapacitor Applications.

作者信息

Parveen Nazish, Ansari Sajid Ali, Alamri Hatem R, Ansari Mohammad Omaish, Khan Ziyauddin, Cho Moo Hwan

机构信息

School of Chemical Engineering, Yeungnam University, Gyeongsan-si, Gyeongbuk 712-749, South Korea.

Department of Energy & Materials Engineering, Dongguk University, Seoul 100-715, Republic of Korea.

出版信息

ACS Omega. 2018 Feb 7;3(2):1581-1588. doi: 10.1021/acsomega.7b01939. eCollection 2018 Feb 28.

Abstract

SnS is an emerging candidate for an electrode material because of the considerable interlayer spaces in its crystal structures and the large surface area. SnS as a photocatalyst and in lithium ion batteries has been reported. On the other hand, there are only a few reports of their supercapacitor applications. In this study, sheetlike SnS (SL-SnS), flowerlike SnS (FL-SnS), and ellipsoid-like SnS (EL-SnS) were fabricated via a facile solvothermal route using different types of solvents. The results suggested that the FL-SnS exhibited better capacitive performance than the SL-SnS and EL-SnS, which means that the morphology has a significant effect on the electrochemical reaction. The FL-SnS displayed higher supercapacitor performance with a high capacity of approximately ∼431.82 F/g at a current density of 1 A/g. The remarkable electrochemical performance of the FL-SnS could be attributed to the large specific surface area and better average pore size. These results suggest that a suitable solvent is appropriate for the large-scale construction of SnS with different morphologies and also has huge potential in the practical applications of high-performance supercapacitors.

摘要

硫化锡因其晶体结构中存在大量层间空间和较大的表面积,成为一种新兴的电极材料候选物。已有关于硫化锡作为光催化剂以及在锂离子电池中的报道。另一方面,关于其在超级电容器应用方面的报道却很少。在本研究中,通过使用不同类型的溶剂,采用简便的溶剂热法制备了片状硫化锡(SL-SnS)、花状硫化锡(FL-SnS)和椭球状硫化锡(EL-SnS)。结果表明,FL-SnS表现出比SL-SnS和EL-SnS更好的电容性能,这意味着形态对电化学反应有显著影响。在1 A/g的电流密度下,FL-SnS展现出较高的超级电容器性能,具有约431.82 F/g的高比电容。FL-SnS卓越的电化学性能可归因于其较大的比表面积和较好的平均孔径。这些结果表明,合适的溶剂适合大规模构建具有不同形态的硫化锡,并且在高性能超级电容器的实际应用中也具有巨大潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/afc2/6641318/050c568ea5f9/ao-2017-01939x_0001.jpg

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