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用于检测二甲基亚砜中硫化氢和水含量的双功能荧光探针

Dual-Function Fluorescent Probe for Detection of Hydrogen Sulfide and Water Content in Dimethyl Sulfoxide.

作者信息

Wang Hao, Li Yanan, Yang Shaoxiang, Tian Hongyu, Liang Sen, Sun Baoguo

机构信息

Beijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Technology and Business University, Beijing 100048, PR China.

出版信息

ACS Omega. 2019 Jun 19;4(6):10695-10701. doi: 10.1021/acsomega.9b00868. eCollection 2019 Jun 30.

Abstract

To detect hydrogen sulfide (HS) and water content in dimethyl sulfoxide, the fluorescent probe (Probe ) was used, as it not only detects HS but also detects the water content. After HS was added into Probe , the intensity of fluorescence increased and was up to 1300 times. In case the HS concentration was in the range 0-20 μM, it was able to be detected by Probe , and the limit of detection was 0.851 nM. When Probe and HS underwent a reaction, the solution color had some changes. These colors changed in terms of the concentration changes of HS, ranging from colorless to yellow. The Probe test paper only needed to be exposed to hydrogen sulfide gas for 20 s for the color change to occur. Besides, Probe -HS was used to detect water content in dimethyl sulfoxide which ranged from 0 to 100%. The color change of the solution was opposite to that of HS, ranging from yellow to colorless.

摘要

为检测二甲基亚砜中的硫化氢(HS)和水含量,使用了荧光探针(探针 ),因为它不仅能检测HS,还能检测水含量。将HS添加到探针 中后,荧光强度增加,高达1300倍。如果HS浓度在0 - 20 μM范围内,探针 能够检测到它,检测限为0.851 nM。当探针 和HS发生反应时,溶液颜色会发生一些变化。这些颜色根据HS浓度的变化而变化,从无色到黄色。探针 试纸只需暴露在硫化氢气体中20秒就会发生颜色变化。此外,探针 -HS用于检测二甲基亚砜中0%至100%范围内的水含量。溶液的颜色变化与HS相反,从黄色到无色。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b38/6648854/72a74fd49d41/ao-2019-008683_0006.jpg

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