Dai Yun, Feng Xiangqing, Du Haifeng
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
University of Chinese Academy of Sciences, Beijing 100049, China.
Org Lett. 2019 Sep 6;21(17):6884-6887. doi: 10.1021/acs.orglett.9b02512. Epub 2019 Aug 28.
A metal-free hydrogenation of unfunctionalized tetrasubstituted olefins were successfully realized using a combination of B(CF) and PhNMe catalyst. The corresponding products were afforded in 58-98% yields with up to >99:1 / selectivity.
使用B(CF)和PhNMe催化剂的组合成功实现了未官能化四取代烯烃的无金属氢化反应。相应产物的产率为58 - 98%，选择性高达>99:1。
