Zhao Jian-Nan, Kayumov Muzaffar, Wang Dong-Yu, Zhang Ao
CAS Key Laboratory of Receptor Research , Shanghai Institute of Materia Medica (SIMM) , Shanghai 201203 , China.
School of Life Science and Technology , ShanghaiTech University , Shanghai 201210 , China.
Org Lett. 2019 Sep 20;21(18):7303-7306. doi: 10.1021/acs.orglett.9b02584. Epub 2019 Aug 29.
Aryl-heteroatom bonds (C-Het) are almost ubiquitously present in chemical molecules. However, methods for diverse C-Het bond formations from a simple substrate are limited. Herein, we report a convenient and efficient C-S bond transformation of aryl sulfoniums to various C-Het bonds (C-O, C-S, C-Sn, C-Si, C-Se) in the absence of any transition-metal catalyst. These reactions proceeded in mild conditions with a wide substrate scope.
芳基-杂原子键（C-Het）几乎普遍存在于化学分子中。然而，从简单底物形成多种C-Het键的方法有限。在此，我们报道了一种在无任何过渡金属催化剂的情况下，将芳基锍盐方便且高效地转化为各种C-Het键（C-O、C-S、C-Sn、C-Si、C-Se）的方法。这些反应在温和条件下进行，底物范围广泛。
