钯催化芳基锍盐与含磷氢化合物的磷酸化反应——碳-硫键断裂
Palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds C-S bond cleavage.
作者信息
Liu Huijin, Sun Kai, Li Xiaolan, Zhang Jie, Lu Wei, Luo Xuzhong, Luo Haiqing
机构信息
Department of Chemistry & Chemical Engineering, Gannan Normal University Ganzhou 341000 China
出版信息
RSC Adv. 2022 Sep 7;12(39):25280-25283. doi: 10.1039/d2ra04297e. eCollection 2022 Sep 5.
Abstract
Herein we report a novel palladium-catalyzed phosphorylation of arylsulfonium salts with P(O)H compounds C-S bond cleavage under mild conditions. The protocol provides a pragmatic strategy applicable to the synthesis of diverse arylphosphonates.
摘要
在此，我们报道了一种新型的钯催化芳基锍盐与含磷氢化合物的磷酸化反应，该反应在温和条件下实现了碳-硫键的裂解。该方法为合成多种芳基膦酸酯提供了一种实用策略。
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