Tayeb Pegah, H Tayeb Ali
Department of Forest Biomaterials, North Carolina State University, Raleigh, NC 27695, USA.
School of Forest Resources, University of Maine, Orono, ME 04469, USA; Advanced Structures and Composites Center, University of Maine, Orono, ME 04469, USA.
Carbohydr Polym. 2019 Nov 15;224:115149. doi: 10.1016/j.carbpol.2019.115149. Epub 2019 Aug 3.
Recent studies advocate the use of cellulose nanomaterials (CNs) as a sustainable carbohydrate polymer in numerous innovative electronics for their quintessential features such as flexibility, low thermal expansion and self-/directed assembly within multiphase matrices. Herein, we review the contemporary advances in CN-built electrochemical systems and highlight the constructive effects of these nanoscopic entities once engineered in conductive composites, proton exchange membranes (PEMs), electrochromics, energy storage devices and piezoelectric sensors. The adopted strategies and designs are discussed in view of CN roles as copolymer, electrolyte reservoir, binder and separator. Finally, physiochemical attributes and durability of resulting architectures are compared to conventional materials and the possible challenges/solutions are delineated to realize the promising capabilities. The volume of the up-to-present literature in the field indeed implies to nanocellulose overriding importance and the presented angles perhaps shed more lights on prospect of the biosphere's most dominant biomaterial in the energy-related arena that deserve attention.
最近的研究提倡将纤维素纳米材料(CNs)作为一种可持续的碳水化合物聚合物,用于众多创新电子产品中,因为它们具有诸如柔韧性、低热膨胀以及在多相基质中自组装/定向组装等典型特征。在此,我们回顾了基于CN构建的电化学系统的当代进展,并强调了这些纳米级实体一旦被设计到导电复合材料、质子交换膜(PEMs)、电致变色材料、储能装置和压电传感器中所产生的建设性作用。鉴于CN作为共聚物、电解质储存库、粘合剂和隔膜的作用,我们讨论了所采用的策略和设计。最后,将所得结构的物理化学属性和耐久性与传统材料进行了比较,并阐述了可能面临的挑战及解决方案,以实现其有前景的性能。该领域目前的文献数量确实表明了纳米纤维素的至关重要性,而本文所呈现的角度或许能为这种生物圈中最主要的生物材料在能源相关领域的前景提供更多启示,值得关注。