Grafting Hyperbranched Polymers onto TiO Nanoparticles via Thiol-yne Click Chemistry and Its Effect on the Mechanical, Thermal and Surface Properties of Polyurethane Coating.

In this study, we proposed a novel and facile method to modify the surface of TiO nanoparticles and investigated the influence of the surface-modified TiO nanoparticles as an additive in a polyurethane (PU) coating. The hyperbranched polymers (HBP) were grafted on the surface of TiO nanoparticles via the thiol-yne click chemistry to reduce the aggregation of nanoparticles and increase the interaction between TiO and polymer matrices. The grafting of HBP on the TiO nanoparticles surface was investigated by means of X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Fourier transform infrared (FT-IR), nuclear magnetic resonance (NMR) and thermogravimetry analysis (TGA). The thermal and mechanical properties of nanocomposite coatings containing various amounts of TiO nanoparticles were measured by dynamic mechanical thermal (DMTA) and tensile strength measurement. Moreover, the surface structure and properties of the newly prepared nanocomposite coatings were examined. The experimental results demonstrate that the incorporation of the surface-modified TiO nanoparticles can improve the mechanical and thermal properties of nanocomposite coatings. The results also reveal that the surface modification of TiO with the HBP chains improves the nanoparticle dispersion, and the coating surface shows a lotus leaf-like microstructure. Thus, the functional nanocomposite coatings exhibit superhydrophobic properties, good photocatalytic depollution performance, and high stripping resistance.