Suppr超能文献

线性二色性与各向异性半金属少层碲化钼的无损晶体识别

Linear Dichroism and Nondestructive Crystalline Identification of Anisotropic Semimetal Few-Layer MoTe.

作者信息

Zhu Meijie, Zhao Yan, Feng Qingliang, Lu Hua, Zhang Shuqing, Zhang Na, Ma Chaojia, Li Jiafeng, Zheng Jianbang, Zhang Jin, Xu Hua, Zhai Tianyou, Zhao Jianlin

机构信息

MOE Key Laboratory of Material Physics and Chemistry under Extraordinary Conditions, Shaanxi Key Laboratory of Optical Information Technology, School of Science, Northwestern Polytechnical University, Xi'an, 710072, P. R. China.

Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119, P. R. China.

出版信息

Small. 2019 Oct;15(44):e1903159. doi: 10.1002/smll.201903159. Epub 2019 Sep 4.

Abstract

Semimetal 1T' MoTe crystals have attracted tremendous attention owing to their anisotropic optical properties, Weyl semimetal, phase transition, and so on. However, the complex refractive indices (n-ik) of the anisotropic semimetal 1T' MoTe still are not revealed yet, which is important to applications such as polarized wide spectrum detectors, polarized surface plasmonics, and nonlinear optics. Here, the linear dichroism of as-grown trilayer 1T' MoTe single crystals is investigated. Trilayer 1T' MoTe shows obvious anisotropic optical absorption due to the intraband transition of d orbits for Mo atoms and p orbits for Te atoms. The anisotropic complex refractive indices of few-layer 1T' MoTe are experimentally obtained for the first time by using the Pinier equation analysis. Based on the linear dichroism of 1T' MoTe , angle-resolved polarized optical microscopy is developed to visualize the grain boundary and identify the crystal orientation of 1T' MoTe crystals, which is also an excellent tool toward the investigation of the optical absorption properties in the visible range for anisotropic 2D transition metal chalcogenides. This work provides a universal and nondestructive method to identify the crystal orientation of anisotropic 2D materials, which opens up an opportunity to investigate the optical application of anisotropic semimetal 2D materials.

摘要

半金属1T'型碲化钼晶体因其各向异性光学性质、外尔半金属特性、相变等受到了广泛关注。然而,各向异性半金属1T'型碲化钼的复折射率(n-ik)仍未被揭示,这对于偏振宽光谱探测器、偏振表面等离子体激元及非线性光学等应用至关重要。在此,对生长态的三层1T'型碲化钼单晶的线性二向色性展开了研究。三层1T'型碲化钼由于钼原子d轨道及碲原子p轨道的带内跃迁而呈现出明显的各向异性光吸收。通过使用皮涅尔方程分析,首次实验获得了少层1T'型碲化钼的各向异性复折射率。基于1T'型碲化钼的线性二向色性,开发了角分辨偏振光学显微镜以可视化晶界并确定1T'型碲化钼晶体的晶体取向,这也是研究各向异性二维过渡金属硫族化合物在可见光范围内光吸收特性的一种出色工具。这项工作提供了一种通用且无损的方法来识别各向异性二维材料的晶体取向,为研究各向异性半金属二维材料的光学应用开辟了机会。

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验