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作为聚合物共混物(低密度聚乙烯/高抗冲聚苯乙烯)填料的调色剂废粉用于增强导电性

Toner Waste Powder (TWP) as a Filler for Polymer Blends (LDPE/HIPS) for Enhanced Electrical Conductivity.

作者信息

Hammani Salim, Barhoum Ahmed, Nagarajan Sakthivel, Bechelany Mikhael

机构信息

Laboratoire d'Analyse Fonctionnelle des Procédés Chimiques, Faculté des Sciences de l'ingénieur, Université BLIDA1, BLIDA B.P 270, ALGERIE.

Institut Europeen des Membranes, IEM - UMR 5635, ENSCM, CNRS, Univ Montpellier, Montpellier 34090, France.

出版信息

Materials (Basel). 2019 Sep 20;12(19):3062. doi: 10.3390/ma12193062.

Abstract

Rapid urbanization proportionally increases the waste products which force humankind to find a suitable waste management system. This study aims at identifying the possibility of using toner waste powder (TWP) as a filler for fabricating polymer composites for enhanced electrical conductivity of polymer blends. TWP was successfully incorporated into a polymer blend of low-density polyethylene/high impact polystyrene (LDPE/HIPS) at a high loading percentage of up to 20 wt %. Elemental analysis (SEM-EDS and XRF) showed that the main constituents of TWP are carbon and iron with traces of other metals such as Ca, Cs, Ti, Mn, Si. The electrical conductivity of LDPE/HIPS is significantly enhanced by loading the TWP into the polymer blend. The addition of TWP to LDPE/HIPS blend decreases the electrical resistivity of the LDPE/HIPS/TWP composite to ~2.9 × 10 Ohm.cm at 10 wt % of TWP, which is several orders of magnitude lower than that of the neat blend with maintaining the thermal stability of the polymer composite. The prepared polymer composite is lightweight and shows electrical conductivity, thus it can have potential applications in electronic materials and automotive industries.

摘要

快速城市化相应地增加了废弃物,这迫使人类寻找合适的废物管理系统。本研究旨在确定使用碳粉废粉(TWP)作为填料来制造聚合物复合材料以提高聚合物共混物电导率的可能性。TWP 以高达 20 wt% 的高负载百分比成功掺入低密度聚乙烯/高抗冲聚苯乙烯(LDPE/HIPS)的聚合物共混物中。元素分析(SEM-EDS 和 XRF)表明,TWP 的主要成分是碳和铁,还有微量的其他金属,如钙、铯、钛、锰、硅。通过将 TWP 负载到聚合物共混物中,LDPE/HIPS 的电导率显著提高。在 TWP 含量为 10 wt% 时,向 LDPE/HIPS 共混物中添加 TWP 可使 LDPE/HIPS/TWP 复合材料的电阻率降低至约 2.9×10 欧姆·厘米,这比纯共混物低几个数量级,同时保持了聚合物复合材料的热稳定性。制备的聚合物复合材料重量轻且具有导电性,因此在电子材料和汽车工业中可能有潜在应用。

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