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使用声化学设计用于光催化的微流反应器:系统评价文章。

Designing Microflowreactors for Photocatalysis Using Sonochemistry: A Systematic Review Article.

机构信息

Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.

Universidad Cooperativa de Colombia, Calle 50A No. 41-34 Medellín, Colombia.

出版信息

Molecules. 2019 Sep 12;24(18):3315. doi: 10.3390/molecules24183315.

Abstract

Use of sonication for designing and fabricating reactors, especially the deposition of catalysts inside a microreactor, is a modern approach. There are many reports that prove that a microreactor is a better setup compared with batch reactors for carrying out catalytic reactions. Microreactors have better energy efficiency, reaction rate, safety, a much finer degree of process control, better molecular diffusion, and heat-transfer properties compared with the conventional batch reactor. The use of microreactors for photocatalytic reactions is also being considered to be the appropriate reactor configuration because of its improved irradiation profile, better light penetration through the entire reactor depth, and higher spatial illumination homogeneity. Ultrasound has been used efficiently for the synthesis of materials, degradation of organic compounds, and fuel production, among other applications. The recent increase in energy demands, as well as the stringent environmental stress due to pollution, have resulted in the need to develop green chemistry-based processes to generate and remove contaminants in a more environmentally friendly and cost-effective manner. It is possible to carry out the synthesis and deposition of catalysts inside the reactor using the ultrasound-promoted method in the microfluidic system. In addition, the synergistic effect generated by photocatalysis and sonochemistry in a microreactor can be used for the production of different chemicals, which have high value in the pharmaceutical and chemical industries. The current review highlights the use of both photocatalysis and sonochemistry for developing microreactors and their applications.

摘要

超声技术在设计和制造反应器方面的应用,特别是在微反应器内部沉积催化剂,是一种现代方法。有许多报告证明,与分批式反应器相比,微反应器在进行催化反应方面具有更好的效果。与传统的分批式反应器相比,微反应器具有更好的能源效率、反应速率、安全性、更精细的过程控制、更好的分子扩散和传热性能。由于其改进的辐照分布、更好的光线穿透整个反应器深度以及更高的空间照明均匀性,因此将微反应器用于光催化反应也被认为是合适的反应器配置。超声技术已被有效地用于材料合成、有机化合物降解和燃料生产等应用。由于能源需求的增加以及环境污染带来的严格的环境压力,需要开发基于绿色化学的工艺,以更环保和更具成本效益的方式生成和去除污染物。可以在微流控系统中使用超声促进方法在反应器内部进行催化剂的合成和沉积。此外,微反应器中光催化和超声化学产生的协同效应可用于生产具有高附加值的不同化学物质,这些物质在制药和化学工业中有很高的价值。目前的综述强调了光催化和超声化学在开发微反应器及其应用方面的联合使用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77b2/6767219/a793eddd3a8f/molecules-24-03315-g002.jpg

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