Tianjin Key Laboratory of Electronic Materials and Devices, School of Electronics and Information Engineering, Hebei University of Technology, 5340 Xiping Road, Beichen District, Tianjin 300401, P.R. China.
State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun, 130012, China.
Nanoscale. 2019 Nov 7;11(41):19119-19139. doi: 10.1039/c9nr06191f. Epub 2019 Sep 26.
Perovskite quantum dots (QDs) have been hotly pursued in recent decades owing to their quantum confinement effect and defect-tolerant nature. Their unique optical properties, such as high photoluminescence quantum yield (PLQY) approaching unity, narrow emission bandwidth, tunable wavelength spanning the entire visible spectrum, and compatibility with flexible/stretchable electronics, render perovskite QDs promising for next-generation solid lighting sources and information displays. Herein, the advances in perovskite QDs and their applications in LEDs are reviewed. Strategies to fabricate efficient perovskite QDs and device configuration, including material composition design, synthetic methods, surface engineering, and device optimization, are investigated and highlighted. Moreover, the main challenges in perovskite QDs of instability and toxicity (lead-based) are identified, while the solutions undertaken with respect to composition engineering, device encapsulation, and lead-replacement QDs are demonstrated. Meanwhile, perspectives for the further development of perovskite QDs and corresponding LEDs are presented.
钙钛矿量子点(QDs)由于其量子限域效应和缺陷容忍特性,在近几十年中受到了广泛的关注。它们独特的光学性质,如接近 1 的高光致发光量子产率(PLQY)、窄发射带宽、可调谐波长覆盖整个可见光范围以及与柔性/可拉伸电子学的兼容性,使得钙钛矿 QD 有望成为下一代固态照明光源和信息显示器。本文综述了钙钛矿 QD 的进展及其在 LED 中的应用。探讨并强调了制备高效钙钛矿 QD 的策略和器件结构,包括材料组成设计、合成方法、表面工程和器件优化。此外,还确定了钙钛矿 QD 存在不稳定性和毒性(含铅)的主要挑战,同时展示了针对组成工程、器件封装和无铅 QD 所采取的解决方案。同时,还对钙钛矿 QD 和相应的 LED 的进一步发展提出了展望。