Distribution, ecological risk assessment and source identification of heavy metals in surface sediments of Huixian karst wetland, China.

In this study, heavy metals including Cd, Pb, Zn, Mn, Cu, Ni, Cr, As, and Hg, in the surface sediment (0-10 cm) of the Huixian wetland in a karst region were investigated in terms of their spatial distribution, ecological risks, and possible sources. Samples were collected from 13 typical sites throughout the Huixian wetland and were analyzed via inductively coupled plasma-mass spectrometry. The results revealed that the mean concentrations of Cd, Pb, Mn, Cr, As, and Hg were higher than the background and Chinese safe standard values. Based on spatial distribution and ecological risk, the study area was differentiated into three groups of sites with the following order of risk: group 3 > group 2 > group 1. The observed concentrations fluctuated slightly with depth. However, an irregular decreasing trend in the concentration with soil depth was observed among the groups. Multivariate statistical analyses showed that the high accumulation of Cd, Pb, Zn and Cu in the sediments of group 3 sites is due to the natural ancient deposition of minerals rich in heavy metals, while the accumulation of Mn, Cr, As, and Hg is attributed to an anthropogenic origin. Agricultural activities, the use of fertilizers and, pesticides, and local automobile repair stations most probably enriched these heavy metals in the Huixian wetland sediments. Hg and Cd have the highest potential ecological risk, which follows the order Hg > Cd > Pb > As > Ni > Cu > Cr > Mn > Zn. The mean geoaccumulation index (I) values of Pb (0.48) and Hg (1.12) suggested moderate contamination in the study area.