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TiC/BiVO 肖特基结作为一种信号指示剂,用于超灵敏光电化学检测 VEGF。

TiC/BiVO Schottky junction as a signal indicator for ultrasensitive photoelectrochemical detection of VEGF.

机构信息

Key Laboratory of Luminescent and Real-Time Analytical Chemistry (Southwest University), Ministry of Education, College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, P. R. China.

出版信息

Chem Commun (Camb). 2019 Nov 12;55(91):13729-13732. doi: 10.1039/c9cc07108c.

Abstract

A "signal-on" photoelectrochemical (PEC) biosensor was developed for ultrasensitive detection of vascular endothelial growth factor 165 (VEGF165) based on a Ti3C2/BiVO4 Schottky junction, which was a novel sensitized structure with excellent photovoltaic performance, prominent film-forming ability and stability. The generation of a built-in electric field by the Ti3C2/BiVO4 Schottky junction efficiently suppressed the combination of photogenerated electron-hole pairs and enhanced the photocurrent, providing a high initial photocurrent signal for the construction of a photoelectrochemical (PEC) biosensor.

摘要

一种基于 Ti3C2/BiVO4 肖特基结的“信号开启”光电化学(PEC)生物传感器被开发出来,用于超灵敏检测血管内皮生长因子 165(VEGF165)。这是一种具有优异光伏性能、突出成膜能力和稳定性的新型敏化结构。Ti3C2/BiVO4 肖特基结产生的内置电场有效地抑制了光生电子-空穴对的复合,增强了光电流,为光电化学(PEC)生物传感器的构建提供了高初始光电流信号。

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