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天然生物质衍生硬碳和活性炭作为电化学超级电容器电极。

Natural biomass derived hard carbon and activated carbons as electrochemical supercapacitor electrodes.

机构信息

Centre for Nanotechnology Research, Vellore Institute of Technology, Vellore, Tamil Nadu, India.

Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Chennai, 600036, Tamil Nadu, India.

出版信息

Sci Rep. 2019 Nov 8;9(1):16315. doi: 10.1038/s41598-019-52006-x.

Abstract

With every moving day, the aspect that is going to be the most important for modern science and technology is the means to supply sufficient energy for all the scientific applications. As the resource of fossil fuel is draining out fast, an alternative is always required to satisfy the needs of the future world. Limited resources also force to innovate something that can utilise the resource more efficiently. This work is based on a simple synthesis route of biomass derived hard carbon and to exploring the possibility of using it as electrochemical supercapacitors. A cheap, eco-friendly and easily synthesized carbon material is utilized as electrode for electrochemical energy-storage. Four different hard carbons were synthesized from KOH activated banana stem (KHC), phosphoric acid treated banana stem derived carbons (PHC), corn-cob derived hard carbon (CHC) and potato starch derived hard carbons (SHC) and tested as supercapacitor electrodes. KOH-activated hard carbon has provided 479.23 F/g specific capacitance as calculated from its cycle voltammograms. A detailed analysis is done to correlate the results obtained with the material property. Overall, this work provides an in depth analysis of the science behind the components of an electrochemical energy-storage system as well as why the different characterization techniques are required to assess the quality and reliability of the material for electrochemical supercapacitor applications.

摘要

随着每一次搬家,对于现代科学技术来说最重要的方面将是为所有科学应用提供足够能源的手段。由于化石燃料资源迅速枯竭,未来世界的需求总是需要替代品来满足。有限的资源也迫使人们创新出更高效利用资源的东西。这项工作基于生物质衍生硬碳的简单合成路线,并探索了将其用作电化学超级电容器的可能性。一种廉价、环保且易于合成的碳材料被用作电化学储能的电极。从 KOH 活化香蕉茎(KHC)、磷酸处理的香蕉茎衍生碳(PHC)、玉米芯衍生的硬碳(CHC)和马铃薯淀粉衍生的硬碳(SHC)合成了四种不同的硬碳,并将其作为超级电容器电极进行了测试。从循环伏安图计算,KOH 活化硬碳提供了 479.23 F/g 的比电容。对这些结果与材料特性进行了详细的分析。总的来说,这项工作深入分析了电化学储能系统组件背后的科学原理,以及为什么需要不同的表征技术来评估电化学超级电容器应用材料的质量和可靠性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c26b/6841744/4b8213b4eb0f/41598_2019_52006_Fig1_HTML.jpg

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