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通过熔盐法低温合成r-BN纳米片及其性能。

Low temperature synthesis via molten-salt method of r-BN nanoflakes, and their properties.

作者信息

Chen Yang, Wang Xing, Yu Chao, Ding Jun, Deng Chengji, Zhu Hongxi

机构信息

The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, 430081, China.

出版信息

Sci Rep. 2019 Nov 8;9(1):16338. doi: 10.1038/s41598-019-52788-0.

Abstract

r-BN nanoflakes were synthesized using KBH and NHCl as the main raw material in a high-purity nitrogen atmosphere. The effects of salt and salt-free conditions and heating temperature on the synthesis of BN were studied. The molten-salt method was used to synthesize BN at 650 °C, which was 250 °C lower than the BN synthesis method without salt. Furthermore, at 1000 °C the prepared flake-like BN crystals showed good crystallinity, uniform morphology, a particle diameter of 200-300 nm, and a thickness of 40-70 nm. Moreover, the specific surface area of BN was 294.26 m/g. In addition, the BN synthesized at 1100 °C had a large elastic modulus value and good oxidation resistance.

摘要

以KBH和NHCl为主要原料,在高纯氮气气氛中合成了r-BN纳米片。研究了有盐和无盐条件以及加热温度对BN合成的影响。采用熔盐法在650℃合成BN,比无盐BN合成方法低250℃。此外,在1000℃时制备的片状BN晶体结晶性良好,形貌均匀,粒径为200 - 300nm,厚度为40 - 70nm。而且,BN的比表面积为294.26m/g。另外,在1100℃合成的BN具有较大的弹性模量值和良好的抗氧化性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78b0/6841957/76164e2260d7/41598_2019_52788_Fig1_HTML.jpg

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