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卤化物钙钛矿及相关器件路线图

Roadmap on halide perovskite and related devices.

出版信息

Nanotechnology. 2020 Apr 10;31(15):152001. doi: 10.1088/1361-6528/ab59ed. Epub 2019 Nov 21.

Abstract

Since the first report on solid-state perovskite solar cells (PSCs) with ∼10% power conversion efficiency (PCE) and 500 h-stability in 2012, tremendous effort has been being devoted to develop PSCs with higher PCE, longer stability and recycling hazardous lead waste. As a result, PCE over 23% was recorded in 2018 and stability over 10 000 h was reported. Beyond photovoltaics, lead halide perovskite materials demonstrated superb properties when they were applied to flat-panel x-ray detectors and non-volatile resistive switching memory. In this review, the progress of the lead halide perovskite in photovoltaics, x-ray imaging and memristors is investigated. Pb-based PSCs and non-Pb-based PSCs are compared, where technologies of non-Pb-based PSCs are not matured for commercialization. Pb-based PSCs were found to be highly suitable for both terrestrial and space photovoltaics. Higher sensitivity under low dose rate observed from the lead halide perovskite suggests a bright future for perovskite x-ray imaging systems. Moreover, high on/off ratio and low energy consumption observed in resistive switching enables perovskite to be a promising candidate for high density memristors.

摘要

自 2012 年首次报道具有约 10%功率转换效率(PCE)和 500 小时稳定性的固态钙钛矿太阳能电池(PSCs)以来,人们一直在努力开发具有更高 PCE、更长稳定性和回收危险铅废物的 PSCs。结果,2018 年记录的 PCE 超过 23%,并报告了超过 10000 小时的稳定性。除了光伏应用外,卤化铅钙钛矿材料在平板 X 射线探测器和非易失性电阻开关存储器中的应用也表现出了优异的性能。在本综述中,研究了卤化铅钙钛矿在光伏、X 射线成像和忆阻器方面的进展。比较了基于 Pb 的 PSCs 和非 Pb 的 PSCs,其中非 Pb 的 PSCs 技术尚未成熟,无法实现商业化。基于 Pb 的 PSCs 被发现非常适合地面和空间光伏应用。卤化铅钙钛矿在低剂量率下观察到的更高灵敏度表明,钙钛矿 X 射线成像系统具有光明的前景。此外,在电阻开关中观察到的高导通/关断比和低能耗使钙钛矿成为高密度忆阻器的有前途的候选材料。

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