Federal Institute of Education Science and Technology of Pernambuco, Recife, Brazil.
Department of Physics, Federal University of Maranhão, São Luiz, Maranhão, Brazil.
Environ Sci Pollut Res Int. 2020 Jan;27(3):3508-3512. doi: 10.1007/s11356-019-07155-x. Epub 2019 Dec 12.
The use of smart materials, especially the carbon-based nanomaterials, is increasing each day. Among the several carbon-based nanomaterials, graphene quantum dots are one of the most impressive ones, not only by its quantum behavior but due to the adsorption quality conferred by electrostatic interactions from the negatively charged groups as the huge surface area (2.630 m2/g). In this study, we developed and tested graphene quantum dots (GQDs) as smart nano-adsorbents of uranium (U) from the radioactive industry waste. The GQDs were developed in a size range of 160-220 nm using a totally green route. The results showed that the GQDs were capable to adsorb almost 40% of the uranium (U) in alamine 3366 solution. Also, the results demonstrated that using GQDs treatment-like smart nanomaterials for radioactive waste in a volume reduction of almost 90% is achieved, helping the storage process as the final disposal of this material. We may conclude that GQDs may represent a smart device for the treatment of radioactive waste as an alternative of absorbent in the radioactive industry.
智能材料的使用,特别是碳基纳米材料,每天都在增加。在几种碳基纳米材料中,石墨烯量子点是最令人印象深刻的一种,不仅因为它的量子行为,还因为其巨大的表面积(2.630 m2/g)赋予的静电相互作用的吸附质量(2.630 m2/g)。在这项研究中,我们开发并测试了石墨烯量子点(GQDs)作为来自放射性工业废物的铀(U)的智能纳米吸附剂。GQDs 的粒径范围为 160-220nm,采用完全绿色路线制备。结果表明,GQDs 能够吸附几乎 40%的 alamine 3366 溶液中的铀(U)。此外,结果表明,使用 GQDs 处理类似的智能纳米材料,可以将放射性废物的体积减少近 90%,有助于储存过程,作为该材料的最终处置。我们可以得出结论,GQDs 可能代表了一种用于放射性废物处理的智能设备,作为放射性工业中吸附剂的替代品。