包含4,5-双（二硝基甲基）-呋咱酸盐和4,5-双（二硝基甲基）-3-氧代-呋咱酸盐的高能量密度材料
High Energy Density Materials Incorporating 4,5-Bis(dinitromethyl)-Furoxanate and 4,5-Bis(dinitromethyl)-3-Oxy-Furoxanate.
作者信息
Zhai Lianjie, Qu Xiaoni, Wang Bozhou, Bi Fuqiang, Chen Sanping, Fan Xuezhong, Xie Gang, Wei Qing, Gao Shengli
机构信息
State Key Laboratory of Fluorine and Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, China.
Key Laboratory of Synthetic and, Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi, 710069, China.
出版信息
Chempluschem. 2016 Nov;81(11):1156-1159. doi: 10.1002/cplu.201600287. Epub 2016 Jul 29.
3-Oxy-furoxanate is immobilized in a heterometallic energetic metal-organic framework (MOFs). Two furoxan-based MOFs ([Ag K (BDOFO)(BDFO) (H O) ] , [K (BDFO)] ) and a salt ([(BDFO )(NH NH ) (H O)] (BDOFO =4,5-bis(dinitromethyl)-3-oxy-furoxanate, BDFO =4,5-bis(dinitromethyl)-furoxanate) are synthesized and their energetic performance evaluated. This study outlines the systematic investigation of detonation performance of 3-oxy-furoxan and its derivatives.
3-氧代呋咱酸盐固定在一种异金属高能金属有机骨架（MOF）中。合成了两种基于呋咱的MOF（[AgK(BDOFO)(BDFO)(H₂O)]、[K(BDFO)]）和一种盐（[(BDFO)₂(NH₂NH₂)(H₂O)]，BDOFO = 4,5-双（二硝基甲基）-3-氧代呋咱酸盐，BDFO = 4,5-双（二硝基甲基）-呋咱酸盐），并对它们的能量性能进行了评估。本研究概述了对3-氧代呋咱及其衍生物爆轰性能的系统研究。
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