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声电化学在能源与环境中的应用。

Sonoelectrochemistry for energy and environmental applications.

机构信息

Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 52828, South Korea.

Solar Energy Lab, Department of Chemistry, Thiruvalluvar University, Vellore 632 115, India.

出版信息

Ultrason Sonochem. 2020 May;63:104960. doi: 10.1016/j.ultsonch.2020.104960. Epub 2020 Jan 20.

DOI:10.1016/j.ultsonch.2020.104960
PMID:31986327
Abstract

Sonoelectrochemistry is the study of the effects and applications of ultrasonic waves on electrochemical processes. The integration of ultrasound and electrochemistry offers many advantages: fast reaction rates, enhanced surface activation, and increased mass transport at an electrode. Significant progress has been made in advancing basic and applied aspects of sonoelectrochemical techniques, which are herein reviewed by addressing the development and applications of sonoelectrochemical processes in energy and environmental areas. This review examines the experimental procedures that are used in various sonoelectrochemical techniques generally used for the synthesis of energy related materials (e.g., fuel cell electrocatalysts and materials for hydrogen production) and for the degradation of various organic compounds/pollutants. The challenges that remain for the sonoelectrochemical production of energy materials, the degradation of organic pollutants, and their associated reaction pathway mechanism(s) are also discussed. This review also highlights the significant improvements made to date. The provided information in this review may be helpful to scientists working in the research areas of environmental remediation, energy exploitation and exploration, as well as synthetic process-oriented research.

摘要

声电化学是研究超声波对电化学过程的影响和应用的学科。超声与电化学的结合具有许多优点:快速的反应速率、增强的表面活化和电极处的质量传递增加。在推进声电化学技术的基础和应用方面取得了重大进展,本文通过讨论声电化学过程在能源和环境领域的发展和应用来对此进行综述。本文考察了各种声电化学技术中通常用于合成与能源相关的材料(例如燃料电池电催化剂和制氢材料)和降解各种有机化合物/污染物的实验程序。本文还讨论了用于能源材料的声电化学生产、有机污染物的降解以及相关反应途径机制方面仍然存在的挑战。本文综述还强调了迄今为止取得的重大进展。本文提供的信息可能有助于从事环境修复、能源开发和勘探以及面向合成过程的研究等领域的科学家。

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