• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

固态发光芳酰基-S,N-酮缩硫醛具有可调的聚集诱导发射特性。

Solid-State Emissive Aroyl-S,N-Ketene Acetals with Tunable Aggregation-Induced Emission Characteristics.

机构信息

Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstrasse 1, 40225, Düsseldorf, Germany.

Division Biophotonics, Bundesanstalt für Materialforschung und -prüfung (BAM), Department 1, Richard-Willstätter-Strasse 11, 12489, Berlin, Germany.

出版信息

Angew Chem Int Ed Engl. 2020 Jun 15;59(25):10037-10041. doi: 10.1002/anie.201916396. Epub 2020 Mar 10.

DOI:10.1002/anie.201916396
PMID:31990116
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7317214/
Abstract

N-Benzyl aroyl-S,N-ketene acetals can be readily synthesized by condensation of aroyl chlorides and N-benzyl 2-methyl benzothiazolium salts in good to excellent yields, yielding a library of 35 chromophores with bright solid-state emission and aggregation-induced emission characteristics. Varying the substituent from electron-donating to electron-withdrawing enables the tuning of the solid-state emission color from deep blue to red.

摘要

N-苄基芳酰基-S,N-亚氨代乙酮缩醛可通过芳酰氯与 N-苄基 2-甲基苯并噻唑鎓盐缩合反应以良好至优异的产率轻易合成，得到 35 个具有明亮固态发射和聚集诱导发射特性的生色团库。改变取代基的电子给体到电子受体的性质，可使固态发射颜色从深蓝色调至红色调。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83ea/7317214/7434acc65337/ANIE-59-10037-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83ea/7317214/e626d37112ad/ANIE-59-10037-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83ea/7317214/0010e72e5035/ANIE-59-10037-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83ea/7317214/f4ef5cbc01d4/ANIE-59-10037-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83ea/7317214/3e9957c7d872/ANIE-59-10037-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83ea/7317214/7434acc65337/ANIE-59-10037-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83ea/7317214/e626d37112ad/ANIE-59-10037-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83ea/7317214/0010e72e5035/ANIE-59-10037-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83ea/7317214/f4ef5cbc01d4/ANIE-59-10037-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83ea/7317214/3e9957c7d872/ANIE-59-10037-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83ea/7317214/7434acc65337/ANIE-59-10037-g004.jpg

相似文献

1
Solid-State Emissive Aroyl-S,N-Ketene Acetals with Tunable Aggregation-Induced Emission Characteristics.固态发光芳酰基-S,N-酮缩硫醛具有可调的聚集诱导发射特性。
Angew Chem Int Ed Engl. 2020 Jun 15;59(25):10037-10041. doi: 10.1002/anie.201916396. Epub 2020 Mar 10.
2
Communication of Bichromophore Emission upon Aggregation - Aroyl-S,N-ketene Acetals as Multifunctional Sensor Merocyanines.聚集诱导双生发色团的发光特性——酰基-S,N-酮烯腙作为多功能感色体菁染料。
Chemistry. 2021 Sep 20;27(53):13426-13434. doi: 10.1002/chem.202102052. Epub 2021 Aug 1.
3
Diaroyl-S,N-ketene Acetals: Red-Shifted Solid-State and Aggregation-Induced Emitters from a One-Pot Synthesis.二芳酰基-S，N-乙烯酮缩醛：一锅法合成的红移固态和聚集诱导发光体
Chemistry. 2023 Oct 23;29(59):e202301908. doi: 10.1002/chem.202301908. Epub 2023 Sep 14.
4
Asymmetrically bridged aroyl-,-ketene acetal-based multichromophores with aggregation-induced tunable emission.具有聚集诱导可调发射的不对称桥联芳酰基 - ， - 烯酮缩醛基多色团。
Chem Sci. 2022 Apr 12;13(18):5374-5381. doi: 10.1039/d2sc00415a. eCollection 2022 May 11.
5
Alkynylated and triazole-linked aroyl-S,N-ketene acetals: one-pot synthesis of solid-state emissive dyes with aggregation-induced enhanced emission characteristics.炔基化和三唑连接的芳酰基-S,N-烯酮缩醛：具有聚集诱导增强发射特性的固态发光染料的一锅法合成。
Sci Rep. 2023 Sep 1;13(1):14399. doi: 10.1038/s41598-023-41146-w.
6
Solid-State Emission and Aggregate Emission of Aroyl- S,N-Ketene Acetals Are Controlled and Tuned by Their Substitution Pattern.酰基-S,N-酮缩硫醛的固态发光和聚集发光可通过取代模式进行控制和调节。
Chemistry. 2022 Nov 2;28(61):e202202579. doi: 10.1002/chem.202202579. Epub 2022 Oct 13.
7
Aroyl-S,N-Ketene Acetals: Luminous Renaissance of a Class of Heterocyclic Compounds.芳酰基 - S，N - 烯酮缩醛：一类杂环化合物的焕发光芒的复兴
Chemistry. 2023 Nov 16;29(64):e202302067. doi: 10.1002/chem.202302067. Epub 2023 Oct 16.
8
Single molecule aggregation-induced dual and white-light emissive etherified aroyl-,-ketene acetals one-pot synthesis.单分子聚集诱导的双发射和白光发射醚化芳酰基-α-酮烯醇缩醛的一锅法合成
RSC Adv. 2023 Jun 5;13(25):16867-16871. doi: 10.1039/d3ra02935b.
9
The complexometric behavior of selected aroyl-S,N-ketene acetals shows that they are more than AIEgens.所选芳酰基-S，N-烯酮缩醛的络合行为表明它们不仅仅是聚集诱导发光体。
Sci Rep. 2024 May 31;14(1):12565. doi: 10.1038/s41598-024-62100-4.
10
Chemistry of Ketene N,S-Acetals: An Overview.烯酮 N,S-缩醛的化学：概述。
Chem Rev. 2016 Jan 27;116(2):287-322. doi: 10.1021/acs.chemrev.5b00360. Epub 2016 Jan 13.

引用本文的文献

1
Optimized synthesis of aroyl--ketene acetals by omission of solubilizing alcohol cosolvents.通过省去增溶醇共溶剂优化芳酰基 - 乙烯酮缩醛的合成。
Beilstein J Org Chem. 2025 Jun 20;21:1201-1206. doi: 10.3762/bjoc.21.97. eCollection 2025.
2
The complexometric behavior of selected aroyl-S,N-ketene acetals shows that they are more than AIEgens.所选芳酰基-S，N-烯酮缩醛的络合行为表明它们不仅仅是聚集诱导发光体。
Sci Rep. 2024 May 31;14(1):12565. doi: 10.1038/s41598-024-62100-4.
3
Alkynylated and triazole-linked aroyl-S,N-ketene acetals: one-pot synthesis of solid-state emissive dyes with aggregation-induced enhanced emission characteristics.

本文引用的文献

1
Consideration of Molecular Structure in the Excited State to Design New Luminogens with Aggregation-Induced Emission.通过考虑激发态分子结构来设计具有聚集诱导发光特性的新型发光体。
Angew Chem Int Ed Engl. 2019 Jun 24;58(26):8632-8639. doi: 10.1002/anie.201814462. Epub 2019 Apr 1.
2
Highly Efficient Nondoped OLEDs with Negligible Efficiency Roll-Off Fabricated from Aggregation-Induced Delayed Fluorescence Luminogens.高效无掺杂 OLED 器件，由聚集诱导延迟荧光发光材料制备，效率滚降可忽略不计。
Angew Chem Int Ed Engl. 2017 Oct 9;56(42):12971-12976. doi: 10.1002/anie.201706752. Epub 2017 Sep 13.
3
Aggregation-Induced Delayed Fluorescence Based on Donor/Acceptor-Tethered Janus Carborane Triads: Unique Photophysical Properties of Nondoped OLEDs.
炔基化和三唑连接的芳酰基-S,N-烯酮缩醛：具有聚集诱导增强发射特性的固态发光染料的一锅法合成。
Sci Rep. 2023 Sep 1;13(1):14399. doi: 10.1038/s41598-023-41146-w.
4
Single molecule aggregation-induced dual and white-light emissive etherified aroyl-,-ketene acetals one-pot synthesis.单分子聚集诱导的双发射和白光发射醚化芳酰基-α-酮烯醇缩醛的一锅法合成
RSC Adv. 2023 Jun 5;13(25):16867-16871. doi: 10.1039/d3ra02935b.
5
Multicomponent synthesis of chromophores - The one-pot approach to functional π-systems.发色团的多组分合成——功能性π体系的一锅法
Front Chem. 2023 Mar 17;11:1124209. doi: 10.3389/fchem.2023.1124209. eCollection 2023.
6
Solid-State Emission and Aggregate Emission of Aroyl- S,N-Ketene Acetals Are Controlled and Tuned by Their Substitution Pattern.酰基-S,N-酮缩硫醛的固态发光和聚集发光可通过取代模式进行控制和调节。
Chemistry. 2022 Nov 2;28(61):e202202579. doi: 10.1002/chem.202202579. Epub 2022 Oct 13.
7
Asymmetrically bridged aroyl-,-ketene acetal-based multichromophores with aggregation-induced tunable emission.具有聚集诱导可调发射的不对称桥联芳酰基 - ， - 烯酮缩醛基多色团。
Chem Sci. 2022 Apr 12;13(18):5374-5381. doi: 10.1039/d2sc00415a. eCollection 2022 May 11.
8
Modular and stereoselective synthesis of tetrasubstituted vinyl sulfides leading to a library of AIEgens.模块化和立体选择性合成四取代乙烯基硫化物，构建了一系列聚集诱导发光（AIE）化合物库。
Nat Commun. 2021 Dec 15;12(1):7298. doi: 10.1038/s41467-021-27167-x.
9
Communication of Bichromophore Emission upon Aggregation - Aroyl-S,N-ketene Acetals as Multifunctional Sensor Merocyanines.聚集诱导双生发色团的发光特性——酰基-S,N-酮烯腙作为多功能感色体菁染料。
Chemistry. 2021 Sep 20;27(53):13426-13434. doi: 10.1002/chem.202102052. Epub 2021 Aug 1.
10
Cooperatively assembled liquid crystals enable temperature-controlled Förster resonance energy transfer.协同组装的液晶实现温度控制的Förster共振能量转移。
Chem Sci. 2021 Jan 26;12(9):3146-3151. doi: 10.1039/d0sc06838a.
基于给体/受体键合的手性卡硼烷三联体的聚集诱导延迟荧光：无掺杂 OLEDs 的独特光物理性质。
Angew Chem Int Ed Engl. 2016 Jun 13;55(25):7171-5. doi: 10.1002/anie.201603232. Epub 2016 May 4.
4
Bioorthogonal Turn-On Probe Based on Aggregation-Induced Emission Characteristics for Cancer Cell Imaging and Ablation.基于聚集诱导发光特性的生物正交开启探针用于癌细胞成像和消融。
Angew Chem Int Ed Engl. 2016 May 23;55(22):6457-61. doi: 10.1002/anie.201601744. Epub 2016 Apr 15.
5
Aggregation-Induced Emission: Together We Shine, United We Soar!聚集诱导发光：聚则发光，合则腾飞！
Chem Rev. 2015 Nov 11;115(21):11718-940. doi: 10.1021/acs.chemrev.5b00263. Epub 2015 Oct 22.
6
Far-Red and Near-IR AIE-Active Fluorescent Organic Nanoprobes with Enhanced Tumor-Targeting Efficacy: Shape-Specific Effects.具有增强肿瘤靶向疗效的远红和近红外 AIE 活性荧光有机纳米探针：形状特异性效应。
Angew Chem Int Ed Engl. 2015 Jun 15;54(25):7275-80. doi: 10.1002/anie.201501478. Epub 2015 May 7.
7
Biosensing by luminogens with aggregation-induced emission characteristics.具有聚集诱导发光特性的发光体的生物传感。
Chem Soc Rev. 2015 Jul 7;44(13):4228-38. doi: 10.1039/c4cs00325j. Epub 2014 Nov 6.
8
An aggregation-induced-emission platform for direct visualization of interfacial dynamic self-assembly.用于直接可视化界面动态自组装的聚集诱导发光平台。
Angew Chem Int Ed Engl. 2014 Dec 1;53(49):13518-13522. doi: 10.1002/anie.201408757. Epub 2014 Oct 31.
9
Mitochondria-targeted cancer therapy using a light-up probe with aggregation-induced-emission characteristics.线粒体靶向光探针用于具有聚集诱导发光特性的癌症治疗。
Angew Chem Int Ed Engl. 2014 Dec 15;53(51):14225-9. doi: 10.1002/anie.201408897. Epub 2014 Oct 15.
10
Luminous butterflies: efficient exciton harvesting by benzophenone derivatives for full-color delayed fluorescence OLEDs.发光蝴蝶：二苯甲酮衍生物的高效激子俘获用于全彩延迟荧光 OLED。
Angew Chem Int Ed Engl. 2014 Jun 16;53(25):6402-6. doi: 10.1002/anie.201402992. Epub 2014 May 18.