固态发光芳酰基-S,N-酮缩硫醛具有可调的聚集诱导发射特性。
Solid-State Emissive Aroyl-S,N-Ketene Acetals with Tunable Aggregation-Induced Emission Characteristics.
机构信息
Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstrasse 1, 40225, Düsseldorf, Germany.
Division Biophotonics, Bundesanstalt für Materialforschung und -prüfung (BAM), Department 1, Richard-Willstätter-Strasse 11, 12489, Berlin, Germany.
出版信息
Angew Chem Int Ed Engl. 2020 Jun 15;59(25):10037-10041. doi: 10.1002/anie.201916396. Epub 2020 Mar 10.
N-Benzyl aroyl-S,N-ketene acetals can be readily synthesized by condensation of aroyl chlorides and N-benzyl 2-methyl benzothiazolium salts in good to excellent yields, yielding a library of 35 chromophores with bright solid-state emission and aggregation-induced emission characteristics. Varying the substituent from electron-donating to electron-withdrawing enables the tuning of the solid-state emission color from deep blue to red.
N-苄基芳酰基-S,N-亚氨代乙酮缩醛可通过芳酰氯与 N-苄基 2-甲基苯并噻唑鎓盐缩合反应以良好至优异的产率轻易合成，得到 35 个具有明亮固态发射和聚集诱导发射特性的生色团库。改变取代基的电子给体到电子受体的性质，可使固态发射颜色从深蓝色调至红色调。
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