Zhang Da-Wei, Li Meng, Chen Chuan-Feng
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
Chem Soc Rev. 2020 Mar 7;49(5):1331-1343. doi: 10.1039/c9cs00680j. Epub 2020 Jan 30.
Since the first attempt that was made to obtain direct circularly polarized (CP) light from OLEDs by Meijer et al. in 1997, considerable efforts have been devoted to the development of circularly polarized organic light-emitting diodes (CP-OLEDs), particularly in the recent years. Circularly polarized electroluminescence (CPEL) based on OLEDs has attracted increasing interest for its efficient ability to generate CP light directly and wide potential applications in 3D displays, optical data storage, and optical spintronics. In this review, we systematically summarize the recent progress in chiral emitter based OLEDs with CPEL properties including CPEL based on chiral conjugated polymers, CPEL based on chiral metal complexes, and CPEL based on chiral simple organic molecules, especially chiral thermally activated delayed fluorescence (TADF) molecules. We believe that this review will provide a promising perspective of chiral emitter based OLEDs with CPEL properties for a broad range of scientists in different disciplinary areas and attract a growing number of researchers to this fast-growing research field.
自1997年梅杰等人首次尝试从有机发光二极管(OLED)中获得直接圆偏振(CP)光以来,人们在圆偏振有机发光二极管(CP-OLED)的开发方面投入了大量精力,尤其是近年来。基于OLED的圆偏振电致发光(CPEL)因其直接产生CP光的高效能力以及在3D显示、光学数据存储和光学自旋电子学等领域的广泛潜在应用而受到越来越多的关注。在这篇综述中,我们系统地总结了具有CPEL特性的基于手性发光体的OLED的最新进展,包括基于手性共轭聚合物的CPEL、基于手性金属配合物的CPEL以及基于手性简单有机分子,特别是手性热激活延迟荧光(TADF)分子的CPEL。我们相信,这篇综述将为不同学科领域的广大科学家提供基于手性发光体的具有CPEL特性的OLED的前景展望,并吸引越来越多的研究人员进入这个快速发展的研究领域。