Single Atom on the 2D Matrix: An Emerging Electrocatalyst for Energy Applications.

The electrochemical energy conversions play an essential role in the production of sustainable and renewable energy. However, the performance is not up to the mark due to the absence of highly efficient and stable electrocatalysts. Recently, both 2D-matrix and single-atom catalysts (SACs) are two intense research topics in the field of electrocatalysis due to the high activity and stability and to maximize the utilization efficiency. Engineering the materials from 3D to 2D and modification from nanoparticles to single atoms have created a significant enhancement in the electrocatalytic activity. Hybridizing both the 2D matrix and SACs (2DM@SACs) creates a new electronic state in the materials, and that bequeaths with enhancing potentials toward the electrocatalytic activity. The strong covalent interaction between the 2D matrix and SACs tunes the intrinsic activity of the electrocatalysts. In this mini-review, we have discussed the different synthesis methods of 2DM@SACs with a focus on their electrochemical energy applications such as hydrogen evolution, oxygen evolution, oxygen reduction, and carbon dioxide reduction. This mini-review appraises the contribution to the rational proposal for the synthesis of perfect 2DM@SAC catalysts with their electrochemical properties toward energy conversion applications.