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有机笼状哑铃

Organic Cage Dumbbells.

作者信息

Greenaway Rebecca L, Santolini Valentina, Szczypiński Filip T, Bennison Michael J, Little Marc A, Marsh Andrew, Jelfs Kim E, Cooper Andrew I

机构信息

Department of Chemistry and Materials Innovation Factory, University of Liverpool, 51 Oxford Street, Liverpool, L7 3NY, UK.

Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, Wood Lane, London, W12 0BZ, UK.

出版信息

Chemistry. 2020 Mar 23;26(17):3718-3722. doi: 10.1002/chem.201905623. Epub 2020 Mar 3.

Abstract

Molecular dumbbells with organic cage capping units were synthesised via a multi-component imine condensation between a tri-topic amine and di- and tetra-topic aldehydes. This is an example of self-sorting, which can be rationalised by computational modelling.

摘要

带有有机笼状封端单元的分子哑铃通过三齿胺与二齿和四齿醛之间的多组分亚胺缩合反应合成。这是自分类的一个例子,可通过计算建模进行合理分析。

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