铑（I）介导的对映选择性碳-硅键活化中的层状手性传递模型：一项理论研究
Layered Chirality Relay Model in Rh(I)-Mediated Enantioselective C-Si Bond Activation: A Theoretical Study.
作者信息
Liu Shihan, Zhang Tao, Zhu Lei, Liu Fenru, Bai Ruopeng, Lan Yu
机构信息
School of Chemistry and Chemical Engineering and Chongqing Key Laboratory of Theoretical and Computational Chemistry, Chongqing University, Chongqing 400030, P. R. China.
College of Chemistry and Institute of Green Catalysis, Zhengzhou University, Zhengzhou 450001, P. R. China.
出版信息
Org Lett. 2020 Mar 20;22(6):2124-2128. doi: 10.1021/acs.orglett.9b04636. Epub 2020 Feb 3.
A three-layer chirality relay model is proposed for Rh(I)-mediated enantioselective siletane activation. A chiral ligand in the back layer controls the position of the alkyne-coordinated metal center in the middle layer, which then provides a chiral environment for the incoming substrate at the front layer. A two-dimensional contour map analysis further clarified this model.
针对铑（I）介导的对映选择性硅杂环丁烷活化，提出了一种三层手性传递模型。后层中的手性配体控制中层炔烃配位金属中心的位置，进而为前层中进入的底物提供手性环境。二维等高线图分析进一步阐明了该模型。
Zotero 插件