Na-gated water-conducting nanochannels for boosting CO conversion to liquid fuels.

Robust, gas-impeding water-conduction nanochannels that can sieve water from small gas molecules such as hydrogen (H), particularly at high temperature and pressure, are desirable for boosting many important reactions severely restricted by water (the major by-product) both thermodynamically and kinetically. Identifying and constructing such nanochannels into large-area separation membranes without introducing extra defects is challenging. We found that sodium ion (Na)-gated water-conduction nanochannels could be created by assembling NaA zeolite crystals into a continuous, defect-free separation membrane through a rationally designed method. Highly efficient in situ water removal through water-conduction nanochannels led to a substantial increase in carbon dioxide (CO) conversion and methanol yield in CO hydrogenation for methanol production.