A new type low-cost, flexible and wearable tertiary nanocomposite sensor for room temperature hydrogen gas sensing.

This paper reports on reduced graphene oxide (rGO), tin oxide (SnO) and polyvinylidene fluoride (PVDF) tertiary nanocomposite thick film based flexible gas sensor. The nanocomposite of 0.90(PVDF) - 0.10[x(SnO) - (1 - x)rGO] with different weight percentages (x = 0, 0.15, 0.30, 0.45, 0.6, 0.75, 0.90 and 1) have been prepared by the hot press method. Chromium (Cr) has been deposited on the surface by using E-beam evaporation system, which is used as electrode of the device. Crystal structure, morphology, and electrical characteristics of the device have been explored for the technological application. A correlation between crystallinity, morphology, and electrical properties with these thick films has also been established. The device has been tested at different hydrogen (H) gas concentration as well as at different response times. A superior response of 0.90(PVDF) - 0.10[0.75(SnO) - 0.25 rGO] nanocomposite thick film has been observed. Hence, this composition is considered as optimized tertiary nanocomposite for the hydrogen gas sensor application. The sensor response of 49.2 and 71.4% with response time 34 sec and 52 sec for 100 PPM and 1000 PPM H gas concentration respectively have been obtained. First time a new kind of low cost and flexible polymer based nanocomposite thick film gas sensor has been explored.