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基于芳基硼酸与汞物种的置换反应的荧光探针快速灵敏地检测无机汞物种和甲基汞。

Fast and sensitive fluorescent detection of inorganic mercury species and methylmercury using a fluorescent probe based on the displacement reaction of arylboronic acid with the mercury species.

机构信息

Department of Chemistry and Chemical Engineering, Inha University, South Korea.

出版信息

Chem Commun (Camb). 2020 Mar 7;56(19):2941-2944. doi: 10.1039/c9cc09240d. Epub 2020 Feb 10.

DOI:10.1039/c9cc09240d
PMID:32040107
Abstract

We present a reaction-based fluorescent probe (1) for Hg and CHHg, based on the displacement reaction of the arylboronic acid with the mercury species. 1 showed promising sensing properties for Hg and CHHg, such as high selectivity and sensitivity, turn-on response, fast response to Hg (<2 min) and CHHg (<5 min), low detection limits and operation in purely aqueous solutions.

摘要

我们提出了一种基于反应的荧光探针(1),用于检测 Hg 和 CHHg,其原理是基于芳基硼酸与汞物种的取代反应。1 对 Hg 和 CHHg 表现出了良好的传感性能,例如高选择性和灵敏度、开环响应、对 Hg(<2 分钟)和 CHHg(<5 分钟)的快速响应、低检测限以及在纯水溶液中的操作。

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