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偶氮染料的分类、性质、近期合成方法及应用

Classifications, properties, recent synthesis and applications of azo dyes.

作者信息

Benkhaya Said, M'rabet Souad, El Harfi Ahmed

机构信息

Laboratory Agro-Resources, Polymers and Process Engineering (LARPOGP)/Organic and Polymer Chemistry, Faculty of Sciences, University Ibn Tofail, Morocco.

Laboratory of Geosciences and Environment, Team Development Geo Resource and Renovation Territories, Faculty of Science, University Ibn Tofail, Kenitra, Morocco.

出版信息

Heliyon. 2020 Jan 31;6(1):e03271. doi: 10.1016/j.heliyon.2020.e03271. eCollection 2020 Jan.

Abstract

In this work, we have presented a very detailed review of the different classification of azo dyes as a function of the number of azo groups and the appropriate functional groups. Then we pointed out some chemical properties of these dyes such as reactivity, isomerization and tautomerism and listed. In the following, we have summarized some recent syntheses of azo dyes and the mechanism of azo dyepolymer conjugation. Finally, we indicate the principle of Gewald's reaction and its application to the synthesis of new azo dyes.

摘要

在这项工作中,我们对偶氮染料根据偶氮基团数量和适当官能团进行的不同分类进行了非常详细的综述。然后我们指出了这些染料的一些化学性质,如反应性、异构化和互变异构,并进行了列举。接下来,我们总结了偶氮染料的一些近期合成方法以及偶氮染料-聚合物共轭的机理。最后,我们阐述了格瓦尔德反应的原理及其在新型偶氮染料合成中的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6a19/7002841/1d20bcb1363f/gr1.jpg

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