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二维 TiCT MXene/GO 杂化膜用于高效渗透发电。

Two-Dimensional TiCT MXene/GO Hybrid Membranes for Highly Efficient Osmotic Power Generation.

机构信息

School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, United States.

出版信息

Environ Sci Technol. 2020 Mar 3;54(5):2931-2940. doi: 10.1021/acs.est.9b05100. Epub 2020 Feb 24.

Abstract

Osmotic power has emerged as one of the promising candidates for clean and renewable energy. However, the advancement of present osmotic power-harvesting technologies, specifically pressure-retarded osmosis (PRO) in this work, is hindered by the unsatisfactory membrane transport properties. Herein, we demonstrate the freestanding transition-metal carbides and graphene oxide hybrid membranes as high-performance PRO membranes. Due to the elimination of internal concentration polarization, the freestanding hybrid membrane can achieve a record-high power density up to approximately 56.4 W m with 2.0 M NaCl as the draw solution and river water (0.017 M) as the feed water at an applied hydraulic pressure difference of 9.66 bar. In addition, the hybrid membranes exhibit enhanced antifouling potential and antibacterial activity. The facile fabrication of the hybrid membranes shed light on a new membrane development platform for the highly anticipated osmotic power-harvesting technologies.

摘要

渗透能作为一种有前途的清洁可再生能源已经崭露头角。然而,目前的渗透能采集技术(在此项工作中特指压力延迟渗透 PRO)的发展受到了不理想的膜传输性能的阻碍。在本文中,我们展示了独立式过渡金属碳化物和氧化石墨烯混合膜作为高性能 PRO 膜。由于消除了内部浓度极化,独立式混合膜可以在 9.66 巴的施加水压差下,以 2.0 M NaCl 作为汲取液和河水(0.017 M)作为进料水,实现高达约 56.4 W m 的创纪录高功率密度。此外,混合膜还表现出增强的抗污染潜力和抗菌活性。混合膜的制备方法简单,为备受期待的渗透能采集技术提供了一个新的膜开发平台。

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