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甘蔗渣半纤维素膜的制备与表征

Preparation and Characterization of Hemicellulose Films from Sugarcane Bagasse.

作者信息

da Silva Braga Roberta, Poletto Matheus

机构信息

Chemical Engineering, University of Caxias do Sul (UCS), Caxias do Sul 95070-560, Brazil.

Postgraduate Program in Engineering of Processes and Technologies (PGEPROTEC), University of Caxias do Sul (UCS), Caxias do Sul 95070-560, Brazil.

出版信息

Materials (Basel). 2020 Feb 20;13(4):941. doi: 10.3390/ma13040941.

Abstract

Hemicellulose is one of the most common polysaccharides found in nature. Its use as a green and sustainable raw material for industries is desirable. In this work, an alkaline-alcoholic method was used to extract hemicelluloses from sugarcane bagasse. After extraction, films with 2%, 3% and 4% (w/v) hemicellulose were produced. The films' morphology, thickness, water solubility, tensile properties and thermal stability were evaluated. The Fourier Transform Infrared Spectroscopy (FTIR) results reveal that the method used removes the hemicellulose from bagasse with a low concentration of lignin. The films presented a compact and dense structure with uniformity in thickness associated with higher solubility in water. The increase in hemicellulose content increased tensile strength, but reduced the tensile strain of the films. Thermogravimetric analysis indicated that the increase in hemicellulose content reduced the films' thermal stability. Thus, these films may act as useful, biodegradable and environmentally friendly materials for engineering applications.

摘要

半纤维素是自然界中最常见的多糖之一。将其用作工业的绿色可持续原料是很理想的。在这项工作中,采用碱醇法从甘蔗渣中提取半纤维素。提取后,制备了含2%、3%和4%(w/v)半纤维素的薄膜。对薄膜的形态、厚度、水溶性、拉伸性能和热稳定性进行了评估。傅里叶变换红外光谱(FTIR)结果表明,所采用的方法能以低浓度木质素从甘蔗渣中去除半纤维素。薄膜呈现出致密且均匀的结构,厚度均匀,在水中的溶解度较高。半纤维素含量的增加提高了薄膜的拉伸强度,但降低了拉伸应变。热重分析表明,半纤维素含量的增加降低了薄膜的热稳定性。因此,这些薄膜可作为工程应用中有用的、可生物降解且环保的材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/afa7/7079596/1bb4677f4372/materials-13-00941-g001.jpg

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