Roldi-Oliveira Mariana, Diniz Layse M, Elias Anastasia L, Luz Sandra M
Mechanical Department, Technology Faculty, University of Brasília, Brasília 70910-900, Brazil.
Department of Chemical and Materials Engineering, University of Alberta, Donadeo Innovation Centre for Engineering, Edmonton, AB T6G 1H9, Canada.
Polymers (Basel). 2022 Jul 25;14(15):2999. doi: 10.3390/polym14152999.
With growing environmental concerns over synthetic polymers, natural polymeric materials, such as hemicellulose, are considered a good sustainable alternative. Curaua fibers could be an excellent source of biopolymer as they have a relatively high hemicellulose content (15 wt%) and only a small amount of lignin (7 wt%). In this work, hemicellulose was extracted by an alkaline medium using KOH and the influence of the alkali concentration, temperature, and time was studied. A hemicellulose film was produced by water casting and its mechanical, thermal, and morphological properties were characterized. The results show that the best method, which resulted in the highest hemicellulose yield and lowest contamination from lignin, was using 10% (/) KOH concentration, 25 °C, and time of 3 h. The hemicellulose film exhibited better thermal stability and elongation at break than other polymeric films. It also exhibited lower rigidity and higher flexibility than other biodegradable polymers, including polylactic acid (PLA) and polyhydroxybutyrate (PHB).
随着对合成聚合物的环境问题日益关注,天然高分子材料,如半纤维素,被认为是一种良好的可持续替代品。库拉索纤维可能是生物聚合物的优质来源,因为它们具有相对较高的半纤维素含量(15重量%)且仅含有少量木质素(7重量%)。在这项工作中,使用氢氧化钾通过碱性介质提取半纤维素,并研究了碱浓度、温度和时间的影响。通过水铸法制备了半纤维素膜,并对其机械、热和形态性能进行了表征。结果表明,获得最高半纤维素产率和最低木质素污染的最佳方法是使用10%(/)的氢氧化钾浓度、25℃和3小时的时间。与其他聚合物膜相比,半纤维素膜表现出更好的热稳定性和断裂伸长率。与其他可生物降解聚合物,包括聚乳酸(PLA)和聚羟基丁酸酯(PHB)相比,它还表现出较低的刚性和较高的柔韧性。