Institute of Chemistry, The Hebrew University of Jerusalem, Edmond J. Safra Campus, Jerusalem 9190401, Israel.
Molecules. 2020 Feb 20;25(4):959. doi: 10.3390/molecules25040959.
Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.
不对称 1,1-双（硼烷基）烷烃和烯烃是有机双金属等价物，它们在合成中非常重要，因为它们允许 C-B 键的顺序选择性转化。我们综述了 1,1-双（硼烷基）烷烃和烯烃的合成和化学反应性，为合成界提供了信息。在本综述的第一部分，我们披露了不对称 1,1-双硼烷基烷烃的合成和化学反应性。在第二部分，我们描述了不对称 1,1-双（硼烷基）烯烃的合成和化学反应性。
