Department of Chemistry and Pharmacy, University of Erlangen-Nuremberg, Egerlandstr. 1, 91058 Erlangen, Germany.
Dalton Trans. 2020 Apr 21;49(15):4599-4659. doi: 10.1039/c9dt04620h. Epub 2020 Mar 12.
This review covers highlights of the work performed in the van Eldik group on inorganic reaction mechanisms over the past two decades in the form of a personal journey. Topics that are covered include, from NO to HNO chemistry, peroxide activation in model porphyrin and enzymatic systems, the wonder-world of Ru(edta) chemistry, redox chemistry of Ru(iii) complexes, Ru(ii) polypyridyl complexes and their application, relevant physicochemical properties and reaction mechanisms in ionic liquids, and mechanistic insight from computational chemistry. In each of these sections, typical examples of mechanistic studies are presented in reference to related work reported in the literature.
这篇综述以个人历程的形式，概述了过去二十年来 van Eldik 小组在无机反应机制方面的工作重点。涵盖的主题包括从 NO 到 HNO 化学、模型卟啉和酶系统中过氧化物的激活、Ru(edta)化学的奇妙世界、Ru(iii)配合物的氧化还原化学、Ru(ii)多吡啶配合物及其应用、离子液体中的相关物理化学性质和反应机制，以及计算化学提供的反应机制见解。在这些章节中的每一节中，都参考文献中报道的相关工作，提出了典型的机制研究实例。
