• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

通过微晶电子衍射和掠入射广角X射线散射研究有机半导体薄膜的晶体结构和取向

Crystal structure and orientation of organic semiconductor thin films by microcrystal electron diffraction and grazing-incidence wide-angle X-ray scattering.

作者信息

Levine Andrew M, Bu Guanhong, Biswas Sankarsan, Tsai Esther H R, Braunschweig Adam B, Nannenga Brent L

机构信息

Nanoscience Initiative, Advanced Science Research Center, Graduate Center, City University of New York, 85 St. Nicholas Terrace, New York, NY 10031, USA.

Chemical Engineering, School for Engineering of Matter, Transport, and Energy, Arizona State University, Tempe, AZ 85287, USA.

出版信息

Chem Commun (Camb). 2020 Apr 14;56(30):4204-4207. doi: 10.1039/d0cc00119h.

DOI:10.1039/d0cc00119h
PMID:32167510
Abstract

We use microcrystal electron diffraction (MicroED) to determine structures of three organic semiconductors, and show that these structures can be used along with grazing-incidence wide-angle X-ray scattering (GIWAXS) to understand crystal packing and orientation in thin films. Together these complimentary techniques provide unique structural insights into organic semiconductor thin films, a class of materials whose device properties and electronic behavior are sensitively dependent on solid-state order.

摘要

我们使用微晶电子衍射(MicroED)来确定三种有机半导体的结构,并表明这些结构可与掠入射广角X射线散射(GIWAXS)一起用于了解薄膜中的晶体堆积和取向。这些互补技术共同为有机半导体薄膜提供了独特的结构见解,这类材料的器件性能和电子行为敏感地依赖于固态有序性。

相似文献

1
Crystal structure and orientation of organic semiconductor thin films by microcrystal electron diffraction and grazing-incidence wide-angle X-ray scattering.通过微晶电子衍射和掠入射广角X射线散射研究有机半导体薄膜的晶体结构和取向
Chem Commun (Camb). 2020 Apr 14;56(30):4204-4207. doi: 10.1039/d0cc00119h.
2
Thin film structure of tetraceno[2,3-b]thiophene characterized by grazing incidence X-ray scattering and near-edge X-ray absorption fine structure analysis.通过掠入射X射线散射和近边X射线吸收精细结构分析表征的并四苯[2,3-b]噻吩薄膜结构
J Am Chem Soc. 2008 Mar 19;130(11):3502-8. doi: 10.1021/ja0773002. Epub 2008 Feb 23.
3
The active layer morphology of organic solar cells probed with grazing incidence scattering techniques.用掠入射散射技术探测有机太阳能电池的活性层形态。
Adv Mater. 2014 Dec 10;26(46):7692-709. doi: 10.1002/adma.201304187. Epub 2014 Feb 12.
4
Grazing-incidence X-ray diffraction tomography for characterizing organic thin films.用于表征有机薄膜的掠入射X射线衍射断层扫描技术。
J Appl Crystallogr. 2021 Sep 4;54(Pt 5):1327-1339. doi: 10.1107/S1600576721007184. eCollection 2021 Oct 1.
5
Grazing incidence wide angle x-ray scattering at the wiggler beamline BW4 of HASYLAB.在HASYLAB的摆动器光束线BW4处进行掠入射广角X射线散射。
Rev Sci Instrum. 2010 Oct;81(10):105105. doi: 10.1063/1.3488459.
6
Multiple scattering in grazing-incidence X-ray diffraction: impact on lattice-constant determination in thin films.掠入射X射线衍射中的多重散射:对薄膜晶格常数测定的影响
J Synchrotron Radiat. 2016 May;23(Pt 3):729-34. doi: 10.1107/S1600577516003672. Epub 2016 Apr 20.
7
Grazing-incidence X-ray diffraction study of rubrene epitaxial thin films.掠入射 X 射线衍射研究并五苯外延薄膜。
J Synchrotron Radiat. 2012 Sep;19(Pt 5):682-7. doi: 10.1107/S0909049512027562. Epub 2012 Jul 11.
8
Two-dimensional GIWAXS reveals a transient crystal phase in solution-processed thermally converted tetrabenzoporphyrin.二维 GIWAXS 揭示了溶液处理的热转化四苯并卟啉中的瞬态晶体相。
J Phys Chem B. 2013 Nov 21;117(46):14557-67. doi: 10.1021/jp408220e. Epub 2013 Nov 6.
9
Influences of Conjugation Length on Organic Field-Effect Transistor Performances and Thin Film Structures of Diketopyrrolopyrrole-Oligomers.二酮吡咯并吡咯寡聚物的键合长度对有机场效应晶体管性能和薄膜结构的影响。
ACS Appl Mater Interfaces. 2018 Mar 14;10(10):8869-8876. doi: 10.1021/acsami.7b15983. Epub 2018 Mar 1.
10
Elucidation of Diverse Solid-State Packing in a Family of Electron-Deficient Expanded Helicenes via Microcrystal Electron Diffraction (MicroED)*.通过微晶电子衍射(MicroED)阐明缺电子扩展螺旋烯家族中的多种固态堆积结构*
Angew Chem Int Ed Engl. 2021 Feb 1;60(5):2493-2499. doi: 10.1002/anie.202012213. Epub 2020 Nov 27.

引用本文的文献

1
3D Electron Diffraction Structure of an Organic Semiconductor Reveals Conformational Polymorphism.一种有机半导体的3D电子衍射结构揭示了构象多态性。
J Am Chem Soc. 2025 Feb 19;147(7):5669-5678. doi: 10.1021/jacs.4c12734. Epub 2025 Feb 6.
2
: heuristic tool for the efficient reduction of grazing-incidence X-ray scattering data.用于高效简化掠入射X射线散射数据的启发式工具。
J Appl Crystallogr. 2024 Feb 12;57(Pt 2):509-528. doi: 10.1107/S1600576723011159. eCollection 2024 Apr 1.
3
Advances and applications of microcrystal electron diffraction (MicroED).
微晶体电子衍射(MicroED)的进展与应用。
Curr Opin Struct Biol. 2024 Feb;84:102741. doi: 10.1016/j.sbi.2023.102741. Epub 2023 Dec 11.
4
Microcrystal Electron Diffraction for Molecular Design of Functional Non-Fullerene Acceptor Structures.用于功能性非富勒烯受体结构分子设计的微晶电子衍射
Chem Mater. 2021 Feb 9;33(3):966-977. doi: 10.1021/acs.chemmater.0c04111. Epub 2021 Jan 25.
5
True molecular conformation and structure determination by three-dimensional electron diffraction of PAH by-products potentially useful for electronic applications.通过对潜在用于电子应用的 PAH 副产物的三维电子衍射,实现真正的分子构象和结构测定。
IUCrJ. 2023 Jan 1;10(Pt 1):131-142. doi: 10.1107/S205225252201154X.
6
Photomechanochemical control over stereoselectivity in the [2 + 2] photodimerization of acenaphthylene.光机械化学控制苊的[2+2]光二聚反应的立体选择性。
Faraday Discuss. 2023 Jan 5;241(0):266-277. doi: 10.1039/d2fd00122e.
7
Electron Diffraction of 3D Molecular Crystals.三维分子晶体的电子衍射。
Chem Rev. 2022 Sep 14;122(17):13883-13914. doi: 10.1021/acs.chemrev.1c00879. Epub 2022 Aug 15.
8
From Powders to Single Crystals: A Crystallographer's Toolbox for Small-Molecule Structure Determination.从粉末到单晶:用于小分子结构测定的晶体学家工具包。
Mol Pharm. 2022 Jul 4;19(7):2133-2141. doi: 10.1021/acs.molpharmaceut.2c00020. Epub 2022 May 16.
9
Studying membrane proteins with MicroED.用微晶电子衍射技术研究膜蛋白。
Biochem Soc Trans. 2022 Feb 28;50(1):231-239. doi: 10.1042/BST20210911.
10
Efficient Free Triplet Generation Follows Singlet Fission in Diketo-pyrrolopyrrole Polymorphs with Goldilocks Coupling.在具有适宜耦合的二酮吡咯并吡咯多晶型物中,高效的自由三线态激子产生遵循单线态裂变。
J Phys Chem C Nanomater Interfaces. 2021 Jun 10;125(22):12207-12213. doi: 10.1021/acs.jpcc.1c02737. Epub 2021 Jun 1.