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通过绿色抑制剂提高海水淡化厂冷却系统的耐腐蚀性。

Enhancement of corrosion resistance of the cooling systems in desalination plants by green inhibitor.

机构信息

Egyptian Petroleum Research Institute (EPRI), Nasr City, Cairo, Egypt.

Polymers Composites and Hybrids, IMT - Mines Ales, 6, avenue de Clavières, F-30319, Alès cedex, France.

出版信息

Sci Rep. 2020 Mar 16;10(1):4812. doi: 10.1038/s41598-020-61810-9.

Abstract

Taraxacum officinale extract (TOE) has been tested for preventing the corrosion of cooling systems in desalination plants. The inhibition of corrosion effects has been characterized by chemical and electrochemical methods (Mass loss, potentiodynamic polarization and electrochemical impedance spectroscopy) and surface observations. Tests on cooling systems were carried out in seawater environment. The presence of TOE in the re-circulation loop decreases the corrosion of carbon steel by adsorption of TOE compounds on the surface of metal pipes. The optimum TOE concentration was reached at 400 mg L and the inhibition efficiency was higher than 94%. TOE allowed increasing the energy barrier of the corrosion process. SEM, FT-IR and UV spectra observations confirmed that TOE prevents corrosion attacks at the surface of the pipes. HPLC analyses identified the presence of saccharides, organic acids, phenol antioxidant and caffeic acid derivatives in TOE, which may be the active promoters of corrosion inhibition.

摘要

蒲公英提取物 (TOE) 已被测试用于防止海水淡化厂冷却系统的腐蚀。通过化学和电化学方法(质量损失、动电位极化和电化学阻抗谱)和表面观察来表征腐蚀抑制效果。在海水环境中对冷却系统进行了测试。TOE 在再循环回路中的存在通过 TOE 化合物在金属管道表面的吸附来减少碳钢的腐蚀。在 400mg/L 时达到最佳 TOE 浓度,抑制效率高于 94%。TOE 提高了腐蚀过程的能垒。SEM、FT-IR 和 UV 光谱观察证实,TOE 可防止管道表面的腐蚀攻击。HPLC 分析表明,TOE 中存在糖类、有机酸、酚类抗氧化剂和咖啡酸衍生物,它们可能是腐蚀抑制的有效促进剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0279/7075887/0ea9a1e7f3ed/41598_2020_61810_Fig1_HTML.jpg

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