Significant ground-level ozone attributed to lightning-induced nitrogen oxides during summertime over the Mountain West States.

Using lightning flash data from the National Lightning Detection Network with an updated lightning nitrogen oxides (NO) emission estimation algorithm in the Community Multiscale Air Quality (CMAQ) model, we estimate the hourly variations in lightning NO emissions for the summer of 2011 and simulate its impact on distributions of tropospheric ozone (O) across the continental United States. We find that typical summer-time lightning activity across the U.S. Mountain West States (MWS) injects NO emissions comparable to those from anthropogenic sources into the troposphere over the region. Comparison of two model simulation cases with and without lightning NO emissions show that significant amount of ground-level O in the MWS during the summer can be attributed to the lightning NO emissions. The simulated surface-level O from a model configuration incorporating lightning NO emissions showed better agreement with the observed values than the model configuration without lightning NO emissions. The time periods of significant reduction in bias in simulated O between these two cases strongly correlate with the time periods when lightning activity occurred in the region. The inclusion of lightning NO increased daily maximum 8 h O by up to 17 ppb and improved model performance relative to measured surface O mixing ratios in the MWS region. Analysis of model results in conjunction with lidar measurements at Boulder, Colorado during July 2014 corroborated similar impacts of lightning NO emissions on O emissions estimated for other summers is comparable to the 2011 air quality. The magnitude of lightning NO estimates suggesting that summertime surface-level O levels in the MWS region could be significantly influenced by lightning NO.