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大豆油基生物增塑剂对轮胎胎面胶的增塑作用

Plasticization Effect of Bio-Based Plasticizers from Soybean Oil for Tire Tread Rubber.

作者信息

Xu Haoshu, Fan Tao, Ye Neng, Wu Weidong, Huang Daye, Wang Danling, Wang Zhao, Zhang Liqun

机构信息

State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China.

Zhongce Rubber Group Co., Ltd., Hangzhou 310014, China.

出版信息

Polymers (Basel). 2020 Mar 9;12(3):623. doi: 10.3390/polym12030623.

DOI:10.3390/polym12030623
PMID:32182860
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7182930/
Abstract

Modified soybean oil (MSO) is synthesized from soybean oil (SO) and sulfur, aiming to reduce the double bond quantity of SO and avoid harmful effects on the crosslink density and mechanical properties of rubber. MSO modified with different weight percentages of sulfur is then used to plasticize tire tread rubber (TR). It is found that the crosslink density and modulus of MSO- plasticized rubber are significantly improved compared with that of SO-plasticized TR. MSO modified with 6 wt % sulfur (MSO-6%) exhibits the best plasticization effect on TR, thus, the plasticization effect of MSO-6% on TR was further studied by adjusting its additive content. Thereafter, the Mooney viscosity, Payne effect, mechanical property of different amount of MSO-6% plasticized TR are studied to investigate their plasticization effect. At the same additive content of plasticizer, the plasticization effect of MSO-6% and a commonly used aromatic hydrocarbon plasticizer (AO) is compared to determine the potential application of MSO on tire tread rubber. It is found MSO shows similar plasticization effect on TR compared with AO. More important, the aging resistance property and wear resistance property of MSO-6% plasticized rubber are better than those of AO-plasticized rubber. Therefore, MSO-6% is a promising bio-based plasticizer for tire tread rubber.

摘要

改性大豆油（MSO）由大豆油（SO）和硫合成，旨在减少SO的双键数量，并避免对橡胶的交联密度和机械性能产生有害影响。然后，用不同重量百分比的硫改性的MSO用于增塑轮胎胎面胶（TR）。结果发现，与SO增塑的TR相比，MSO增塑橡胶的交联密度和模量有显著提高。用6wt%硫改性的MSO（MSO-6%）对TR表现出最佳的增塑效果，因此，通过调整其添加量进一步研究了MSO-6%对TR的增塑效果。此后，研究了不同用量的MSO-6%增塑TR的门尼粘度、Payne效应和机械性能，以考察它们的增塑效果。在增塑剂添加量相同的情况下，比较了MSO-6%与常用芳烃增塑剂（AO）的增塑效果，以确定MSO在轮胎胎面胶上的潜在应用。结果发现，MSO对TR的增塑效果与AO相似。更重要的是，MSO-6%增塑橡胶的耐老化性能和耐磨性能优于AO增塑橡胶。因此，MSO-6%是一种有前途的用于轮胎胎面胶的生物基增塑剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f41/7182930/885186a06557/polymers-12-00623-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f41/7182930/106c6b8bf8e1/polymers-12-00623-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f41/7182930/e5a90050c03e/polymers-12-00623-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f41/7182930/cad5ebeac9a1/polymers-12-00623-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f41/7182930/885186a06557/polymers-12-00623-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f41/7182930/106c6b8bf8e1/polymers-12-00623-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f41/7182930/e5a90050c03e/polymers-12-00623-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f41/7182930/cad5ebeac9a1/polymers-12-00623-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f41/7182930/885186a06557/polymers-12-00623-g005.jpg

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