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低曲折度水微通道提高高水通量太阳能蒸馏的能量利用率。

Low-Tortuosity Water Microchannels Boosting Energy Utilization for High Water Flux Solar Distillation.

机构信息

State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China.

Department of Civil Engineering, The University of Hong Kong, Pokfulam HW619B, Hong Kong, China.

出版信息

Environ Sci Technol. 2020 Apr 21;54(8):5150-5158. doi: 10.1021/acs.est.9b06072. Epub 2020 Apr 1.

Abstract

Solar distillation through photothermal evaporators has approached solar light energy (E) limit under no solar concentration but still suffers from modest vapor and clean water production. Herein, a nature-inspired low-tortuosity three-dimensional (3D) evaporator is demonstrated to significantly improve water production. The solar evaporator, prepared from polypyrrole-modified maize straw (PMS), had upright vascular structures enabling high water lifting and horizontal microgaps facilitating broad water distribution to the out-surface. Consequently, this novel PMS evaporator dramatically enhanced the utilization of the solar heat energy stored in the environment (E) for promoting evaporation. The maximum vapor generation rate of a single PMS respectively increases 2.5 and 6 times compared with the conventional 3D evaporators and the planar evaporators of an identical occupied area. Consequently, a scaled-up PMS array achieved a state-of-the-art vapor generation rate of 3.0 L m h (LMH) under a simulated condition and a record-high clean water production of 2.2 LMH for actual seawater desalination under natural conditions (1 sun intensity). This breakthrough reveals great potentials for cost-effective freshwater production as well as the rational design of high-performance photothermal evaporators for solar distillation.

摘要

通过光热蒸发器进行太阳能蒸馏,在没有太阳聚光的情况下已经接近太阳能(E)极限,但仍然存在蒸汽产量和清洁水产量低的问题。本文展示了一种受自然启发的低曲折度三维(3D)蒸发器,可以显著提高水产量。该太阳能蒸发器由聚吡咯改性玉米秸秆(PMS)制备而成,具有直立的血管结构,能够实现高水位提升,水平微间隙有助于将水广泛分布到外表面。因此,这种新型 PMS 蒸发器可以极大地提高环境中储存的太阳能(E)的利用率,从而促进蒸发。与传统的 3D 蒸发器和相同占地面积的平面蒸发器相比,单个 PMS 的最大蒸汽生成速率分别提高了 2.5 倍和 6 倍。因此,规模化的 PMS 阵列在模拟条件下实现了 3.0 L m h(LMH)的蒸汽生成速率,在自然条件下(1 个太阳强度)实际海水淡化中实现了创纪录的 2.2 LMH 的清洁水产量。这一突破为低成本淡水生产以及太阳能蒸馏用高性能光热蒸发器的合理设计揭示了巨大的潜力。

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