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源自石墨相氮化碳的氮掺杂碳纳米管的合成与表征

Synthesis and Characterization of Nitrogen-doped Carbon Nanotubes Derived from g-CN.

作者信息

Maślana Klaudia, Kaleńczuk Ryszard J, Zielińska Beata, Mijowska Ewa

机构信息

Nanomaterials Physicochemistry Department, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology, Piastow Av. 45, 70-311 Szczecin, Poland.

出版信息

Materials (Basel). 2020 Mar 17;13(6):1349. doi: 10.3390/ma13061349.

DOI:10.3390/ma13061349
PMID:32192006
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7142548/
Abstract

Here, nitrogen-doped carbon nanotubes (CNT-N) were synthesized using exfoliated graphitic carbon nitride functionalized with nickel oxides (ex-g-CN-NixO). CNT-N were produced at 900 °C in two steps: (1) ex-g-CN-NiO reduction with hydrogen and (2) ethylene assisted chemical vapor deposition (CVD). The detailed characterization of the produced materials was performed via atomic force microscopy (AFM), transmission electron microscopy (TEM), Raman spectroscopy, X-ray diffraction (XRD) and thermogravimetric analysis (TGA). The possible mechanism of nanotubes formation is also proposed.

摘要

在此，使用用氧化镍功能化的剥离石墨相氮化碳（ex-g-CN-NixO）合成了氮掺杂碳纳米管（CNT-N）。CNT-N在900℃下分两步制备：（1）用氢气还原ex-g-CN-NiO和（2）乙烯辅助化学气相沉积（CVD）。通过原子力显微镜（AFM）、透射电子显微镜（TEM）、拉曼光谱、X射线衍射（XRD）和热重分析（TGA）对所制备材料进行了详细表征。还提出了纳米管形成的可能机制。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/71c01a7fcfa8/materials-13-01349-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/253e3b5e8f6e/materials-13-01349-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/cb37e1ade41c/materials-13-01349-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/d9c93a4c1bd1/materials-13-01349-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/6ef5fd3559de/materials-13-01349-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/4e92a5ce3059/materials-13-01349-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/b7f4cd3aa824/materials-13-01349-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/0a24a0d0ab72/materials-13-01349-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/22746807dbab/materials-13-01349-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/d770fc7e8df5/materials-13-01349-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/1d79bafa1b28/materials-13-01349-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/c7970fb68e69/materials-13-01349-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/71c01a7fcfa8/materials-13-01349-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/253e3b5e8f6e/materials-13-01349-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/cb37e1ade41c/materials-13-01349-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/d9c93a4c1bd1/materials-13-01349-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/6ef5fd3559de/materials-13-01349-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/4e92a5ce3059/materials-13-01349-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/b7f4cd3aa824/materials-13-01349-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/0a24a0d0ab72/materials-13-01349-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/22746807dbab/materials-13-01349-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/d770fc7e8df5/materials-13-01349-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/1d79bafa1b28/materials-13-01349-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/c7970fb68e69/materials-13-01349-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df3b/7142548/71c01a7fcfa8/materials-13-01349-g012.jpg

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