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4,4'-(((1E,5E)-戊烷-1,5-二亚基)双(氮杂亚基))双(1-十二烷基吡啶-1-鎓)溴化物作为一种在酸性溶液中的新型缓蚀剂(第一部分)。

4,4'-(((1E,5E)-pentane-1,5-diylidene)bis(azanylylidene))bis(1-dodecylpyridin-1-ium) bromide as a novel corrosion inhibitor in an acidic solution (part I).

机构信息

Egyptian Petroleum Research Institute (EPRI), Nasr City, Cairo 11727, Egypt.

Egyptian Petroleum Research Institute (EPRI), Nasr City, Cairo 11727, Egypt.

出版信息

Mater Sci Eng C Mater Biol Appl. 2020 May;110:110673. doi: 10.1016/j.msec.2020.110673. Epub 2020 Jan 16.

Abstract

The metal corrosion inhibition efficiency of a novel synthesized cationic gemini surfactant (SCGS), namely, 4,4'-(((1E,5E)-pentane-1,5-diylidene)bis(azanylylidene))bis (1-dodecylpyridin-1-ium) bromide, was studied in acidic medium by three techniques. The achieved results displayed the inhibition efficiency of the metal corrosion that was elevated by increasing both the SCGS's concentration and the applied temperature values. Furthermore, it was noticed that the charge transfer resistance value was elevated; however, the constant phase element was decreased with increasing the SCGS concentrations. The SCGS regards an excellent and mixed-type corrosion inhibitor. The adsorption of SCGS has agreed the Langmuir's adsorption isotherm and was related to physisorption and chemisorption.

摘要

新型合成阳离子双子表面活性剂(SCGS),即 4,4'-(((1E,5E)-戊烷-1,5-二亚基)双(氮杂亚基))双(1-十二烷基吡啶-1-鎓)溴化物,在酸性介质中通过三种技术研究了其对金属腐蚀的抑制效率。结果表明,随着 SCGS 浓度和施加温度的升高,金属腐蚀的抑制效率得到提高。此外,还注意到随着 SCGS 浓度的增加,电荷转移电阻值升高,而恒相元件值降低。SCGS 是一种优良的混合型腐蚀抑制剂。SCGS 的吸附符合 Langmuir 吸附等温线,与物理吸附和化学吸附有关。

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