Egyptian Petroleum Research Institute (EPRI), Nasr, Cairo 11727, Egypt.
Bioproducts Research Chair, Zoology Department, College of Science, King Saud University, Riyadh 11451, Saudi Arabia.
Molecules. 2020 Mar 16;25(6):1348. doi: 10.3390/molecules25061348.
The Egyptian petroleum industries are incurring severe problems with corrosion, particularly corrosion that is induced by sulfidogenic microbial activities in harsh salinity environments despite extensively using biocides and metal corrosion inhibitors. Therefore, in this study, a synthesized cationic gemini surfactant (SCGS) was tested as a broad-spectrum antimicrobial, anti-bacterial, anti-candida, anti-fungal, anti-biofilm (anti-adhesive), and bio-dispersion agent. The SCGS was evaluated as a biocide against environmental sulfidogenic-bacteria and as a corrosion inhibitor for a high salinity cultivated medium. The SCGS displayed wide spectrum antimicrobial activity with minimum bactericidal/fungicidal inhibitory concentrations. The SCGS demonstrated anti-bacterial, anti-biofilm, and bio-dispersion activity. The SCGS exhibited bactericidal activity against environmental sulfidogenic bacteria and the highest corrosion inhibition efficiency of 93.8% at 5 mM. Additionally, the SCGS demonstrated bio-dispersion activity against the environmental sulfidogenic bacteria at 5.49% salinity. In conclusion, this study provides a novel synthesized cationic surfactant with many applications in the oil and gas industry: as broad-spectrum antimicrobial and anti-biofilm agents, corrosion inhibition for high salinity, biocides for environmentally sulfidogenic bacteria, and as bio-dispersion agents.
埃及石油工业在面临严重的腐蚀问题,尤其是在恶劣盐度环境中,由硫化物产生的微生物活动引起的腐蚀问题,尽管广泛使用杀生剂和金属腐蚀抑制剂。因此,在本研究中,合成了一种阳离子双子表面活性剂(SCGS),用作广谱抗菌、抗细菌、抗真菌、抗生物膜(抗黏附)和生物分散剂。SCGS 被评估为一种针对环境硫化物产生细菌的杀生剂,以及一种用于高盐度培养介质的腐蚀抑制剂。SCGS 表现出宽谱抗菌活性,具有最低杀菌/抑菌浓度。SCGS 表现出抗细菌、抗生物膜和生物分散活性。SCGS 对环境硫化物产生细菌表现出杀菌活性,在 5mM 时最高腐蚀抑制效率为 93.8%。此外,SCGS 在 5.49%盐度下对环境硫化物产生细菌表现出生物分散活性。总之,本研究提供了一种新型合成阳离子表面活性剂,在石油和天然气工业中有许多应用:作为广谱抗菌和抗生物膜剂、高盐度腐蚀抑制剂、环境硫化物产生细菌的杀生剂以及生物分散剂。