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一种源自美利奴羊毛/尼龙聚合物纳米复合材料的多功能智能纺织品,用作下一代微波吸收器和柔软触感传感器。

A Multifunctional Smart Textile Derived from Merino Wool/Nylon Polymer Nanocomposites as Next Generation Microwave Absorber and Soft Touch Sensor.

作者信息

Ghosh Sabyasachi, Nitin B, Remanan Sanjay, Bhattacharjee Yudhajit, Ghorai Arup, Dey Tamal, Das Tushar Kanti, Das Narayan Ch

机构信息

Rubber Technology Centre, Indian Institute of Technology, Kharagpur, 721302, India.

Cryogenic Engineering Centre, Indian Institute of Technology, Kharagpur, 721302, India.

出版信息

ACS Appl Mater Interfaces. 2020 Apr 15;12(15):17988-18001. doi: 10.1021/acsami.0c02566. Epub 2020 Apr 1.

Abstract

In recent times e-textiles have emerged as wonder safeguards due to the great potential background in space, military, healthcare, or portable electronics. As a result, widespread research and development have been done to make significant advancement in this field, but it still remains a key challenge to use one single product with multifunctional attributes with the past performance of key characteristics. In this work, phase-separated PEDOT:PSS ornamented with reduced graphene oxide (rGO) nanosheets, deposited on the newly fabricated ultralightweight, superhydrophobic, and mechanically enriched merino wool/nylon (W-N) composite textile followed by the dipping and drying strategy. The open edges-layered structure of rGO helping uniform deposition of PEDOTs clusters, which allows the formation of a stacked layer of PEDOTs/rGO-PEDOTs/PEDOTs for robust three-dimensional electrical transforming channel network within the W-N textile surface. These dip-coated multifunctional textiles show high electrical conductivities up to 90.5 S cm conjugated with a flexible electromagnetic interference shielding efficiency of 73.8 dB (in X-band) and in-plane thermal conductivity of 0.81 W/mK with a minimum thickness of 0.84 mm. This thin coating maintained the hydrophobicity (water contact angle of ∼150°) leading to an excellent EM protective cloth combined with real-life antenna performance under high mechanical or chemical tolerance. Interestingly, this multiuse textile can also act as an exceptional TASER Proof Textile (TPT) due to a short out of the electrical shock coming from the TASER by its unique conducting network architecture. Remarkably, this coated textile can get a response by the soft touch to lighten up the household bulb and could establish wireless communication via an HC-05 Bluetooth module as a textile-based touch switch. This developed fabric could perform as a new potentially scalable single product in intelligent smart garments, portable next-generation electronics, and the growing threat of EM pollution.

摘要

近年来,电子纺织品因其在太空、军事、医疗保健或便携式电子产品等领域的巨大潜在背景而成为神奇的防护产品。因此,人们进行了广泛的研发工作,以在该领域取得重大进展,但要使用具有多功能属性且具备关键特性以往性能的单一产品,仍然是一项关键挑战。在这项工作中,通过浸渍和干燥策略,将装饰有还原氧化石墨烯(rGO)纳米片的相分离聚(3,4-乙撑二氧噻吩):聚苯乙烯磺酸盐(PEDOT:PSS)沉积在新制备的超轻、超疏水且机械性能增强的美利奴羊毛/尼龙(W-N)复合纺织品上。rGO的开放边缘分层结构有助于PEDOTs簇的均匀沉积,从而在W-N纺织品表面形成用于稳健三维电转换通道网络的PEDOTs/rGO-PEDOTs/PEDOTs堆叠层。这些浸涂的多功能纺织品显示出高达90.5 S/cm的高电导率,同时具有73.8 dB(X波段)的灵活电磁干扰屏蔽效率以及0.81 W/mK的面内热导率,最小厚度为0.84 mm。这种薄涂层保持了疏水性(水接触角约为150°),从而形成了一种优异的电磁防护布,并在高机械或化学耐受性下具备实际的天线性能。有趣的是,这种多用途纺织品还可以作为一种特殊的防电击纺织品(TPT),因为其独特的导电网络结构能够在短时间内消除来自电击枪的电击。值得注意的是,这种涂层纺织品通过轻触就能做出反应,点亮家用灯泡,并可以通过HC-05蓝牙模块作为基于纺织品的触摸开关建立无线通信。这种开发的织物可以在智能服装、便携式下一代电子产品以及日益严重的电磁污染威胁中作为一种新的潜在可扩展单一产品发挥作用。

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