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具有用于运动检测和电磁干扰屏蔽的银-铟镓合金导电层的超疏水电子织物。

Superhydrophobic E-textile with an Ag-EGaIn Conductive Layer for Motion Detection and Electromagnetic Interference Shielding.

作者信息

Sun Xinlong, Fu Jun-Heng, Teng Chao, Zhang MingKuan, Liu TianYing, Guo MingHui, Qin Peng, Zhan Fei, Ren Yan, Zhao Hongbin, Wang Lei, Liu Jing

机构信息

Beijing Key Lab of Cryo-biomedical Engineering and Key Lab of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.

School of Textile Science and Engineering, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, People's Republic of China.

出版信息

ACS Appl Mater Interfaces. 2022 Jul 15. doi: 10.1021/acsami.2c09554.

Abstract

As as emerging innovation, electronic textiles have shown promising potential in health monitoring, energy harvesting, temperature regulation, and human-computer interactions. To access broader application scenarios, numerous e-textiles have been designed with a superhydrophobic surface to steer clear of interference from humidity or chemical decay. Nevertheless, even the cutting-edge electronic textiles (e-textiles) still have difficulty in realizing superior conductivity and satisfactory water repellency simultaneously. Herein, a facile and efficient approach to integrate a hierarchical elastic e-textile is proposed by electroless silver plating on GaIn alloy liquid metal coated textiles. The continuous uneven surface of AgNPs and deposition of FAS-17 endow the textile with exceptional and robust superhydrophobic performance, in which the conductivity and the contact angle of the as-made textile could reach 2145 ± 122 S/cm and 161.5 ± 2.1°, respectively. On the basis of such excellent conductivity, the electromagnetic interference (EMI) shielding function is excavated and the average shielding efficiency (SE) reaches about 87.56 dB within frequencies of 8.2-12.4 GHz. Furthermore, due to its high elasticity and low modulus, the textile can serve as a wearable strain sensor for motion detection, health monitoring, and underwater message transmission. This work provides a novel route to fabricate high-performance hydrophobic e-textiles, in which the encapsulation strategy could be referenced for the further development of conductive textiles.

摘要

作为一种新兴的创新技术,电子纺织品在健康监测、能量收集、温度调节和人机交互方面展现出了广阔的潜力。为了拓展更广泛的应用场景,许多电子纺织品被设计成具有超疏水表面,以避免受到湿度或化学腐蚀的干扰。然而,即使是最先进的电子纺织品,在同时实现优异的导电性和令人满意的防水性方面仍存在困难。在此,通过在涂覆有镓铟合金液态金属的纺织品上进行化学镀银,提出了一种简便有效的方法来制备具有分层结构的弹性电子纺织品。银纳米颗粒连续不平坦的表面和全氟辛烷磺酸-17的沉积赋予了该纺织品卓越且稳定的超疏水性能,所制备纺织品的电导率和接触角分别可达2145±122 S/cm和161.5±2.1°。基于如此优异的导电性,挖掘出了电磁干扰(EMI)屏蔽功能,在8.2-12.4 GHz频率范围内平均屏蔽效率(SE)达到约87.56 dB。此外,由于其高弹性和低模量,该纺织品可作为可穿戴应变传感器用于运动检测、健康监测和水下信息传输。这项工作为制备高性能疏水性电子纺织品提供了一条新途径,其中的封装策略可为导电纺织品的进一步发展提供参考。

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