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特刊:“均相催化进展”。

Special Issue: "Advances in Homogeneous Catalysis".

机构信息

Laboratorio de Compuestos Organometálicos y Catálisis (Unidad Asociada al CSIC), Departamento de Química Orgánica e Inorgánica, (IUQOEM), Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Química, Universidad de Oviedo, E-33071 Oviedo, Spain.

出版信息

Molecules. 2020 Mar 25;25(7):1493. doi: 10.3390/molecules25071493.

Abstract

The use of enzymes, organo-catalysts or transition metal catalysts, as opposed to the employment of stoichiometric quantities of other traditional promoters of different organic synthetic processes (like, inorganic/organic bases, Brønsted acids, radicals, etc.) has allowed the discovery of a great number of new synthetic protocols within the toolbox of organic chemists. Moreover, the employment of the aforementioned catalysts in organic synthesis permits: () the diminution of the global energy demand and production cost; () the enhancement of both the chemoselectivity and stereoselectivity of the global process; and () the reduction of metal-, organo- or bio-catalyst consumption, thanks to the possible recycling of the catalysts; all these being synthetic concepts closely related with the principles of so-called Thus, this Special Issue on "" has been aimed to showcase a series of stimulating contributions from international experts within different sub-areas of catalysis in organic synthesis (ranging from metal-, organo-, or bio-catalyzed organic reactions).

摘要

酶、有机催化剂或过渡金属催化剂的使用,与不同有机合成过程中使用化学计量的其他传统促进剂(如无机/有机碱、布朗斯台德酸、自由基等)相反,使得化学家在有机化学工具箱中发现了大量新的合成方案。此外,上述催化剂在有机合成中的应用允许:(i)降低全球能源需求和生产成本;(ii)提高整体过程的化学选择性和立体选择性;(iii)减少金属、有机或生物催化剂的消耗,因为催化剂可以回收利用;所有这些都是与所谓的可持续化学密切相关的合成概念。因此,本期关于“可持续有机合成中的催化”的特刊旨在展示来自不同催化子领域的国际专家的一系列富有启发性的贡献(范围从金属、有机或生物催化的有机反应)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe64/7181144/bf21316ed396/molecules-25-01493-sch001.jpg

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