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以不锈钢为固体还原剂合成金纳米粒子：批判性综述

Gold Nanoparticles Synthesis Using Stainless Steel as Solid Reductant: A Critical Overview.

作者信息

Izzi Margherita, Sportelli Maria C, Tursellino Luciana, Palazzo Gerardo, Picca Rosaria A, Cioffi Nicola, López Lorente Ángela I

机构信息

Department of Chemistry, University of Bari "Aldo Moro", Via Orabona, 4, 70126 Bari, Italy.

Departamento de Química Analítica, Instituto Universitario de Investigación en Química Fina y Nanoquímica IUIQFN, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie, E-14071 Córdoba, Spain.

出版信息

Nanomaterials (Basel). 2020 Mar 27;10(4):622. doi: 10.3390/nano10040622.

DOI:10.3390/nano10040622
PMID:32230948
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7221709/
Abstract

Gold nanoparticles (AuNPs) were produced using stainless steel as a solid reductant to assist the synthesis of metal NPs, using HAuCl as a precursor. This method is very easy, quick, and cost-effective, allowing the synthesis of highly stable NPs without additional capping agents. However, the reaction mechanism is still under debate. In order to contribute to the investigation of the synthesis of AuNPs using stainless steel, different experimental conditions were tested. Cl concentration, pH of the precursor solution, as well as stainless steel composition were systematically changed. The syntheses were performed recording the open circuit potential to potentiometrically explore the electrochemical properties of the system, under conditions. Spectroscopic and morphological characterizations were carried out along with potentiometric monitoring, aiming at correlating the synthesis parameters with the AuNPs characteristics. As a result, an overview of the process features, and of its most reasonable mechanism were obtained.

摘要

以不锈钢作为固体还原剂，以氯金酸为前驱体，制备了金纳米颗粒（AuNPs）以辅助金属纳米颗粒的合成。该方法非常简便、快速且具有成本效益，无需额外的封端剂即可合成高度稳定的纳米颗粒。然而，其反应机理仍存在争议。为了有助于研究使用不锈钢合成AuNPs的过程，测试了不同的实验条件。系统地改变了氯离子浓度、前驱体溶液的pH值以及不锈钢的成分。在特定条件下，通过记录开路电位进行合成，以电位法探究该体系的电化学性质。在电位监测的同时进行了光谱和形态表征，旨在将合成参数与AuNPs的特性相关联。结果，获得了该过程特征及其最合理机理的概述。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/113b881d87c0/nanomaterials-10-00622-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/bddc2d2875e0/nanomaterials-10-00622-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/9e36136f4e3e/nanomaterials-10-00622-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/231d6f7a6fa9/nanomaterials-10-00622-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/113b881d87c0/nanomaterials-10-00622-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/e30b4fdbcdfa/nanomaterials-10-00622-g002.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/43f66ffbab61/nanomaterials-10-00622-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/9ae3455baf2d/nanomaterials-10-00622-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/6aeeed81091d/nanomaterials-10-00622-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/fc9455304b5f/nanomaterials-10-00622-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/9e36136f4e3e/nanomaterials-10-00622-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/231d6f7a6fa9/nanomaterials-10-00622-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2dd/7221709/113b881d87c0/nanomaterials-10-00622-g011.jpg

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本文引用的文献

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Mater Sci Eng C Mater Biol Appl. 2019 Oct;103:109805. doi: 10.1016/j.msec.2019.109805. Epub 2019 May 28.
2
An Overview of the Synthesis of Gold Nanoparticles Using Radiation Technologies.利用辐射技术合成金纳米粒子的综述。
Nanomaterials (Basel). 2018 Nov 15;8(11):939. doi: 10.3390/nano8110939.
3
Antimicrobial activity and toxicity of gold nanoparticles: research progress, challenges and prospects.
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Lett Appl Microbiol. 2018 Dec;67(6):537-543. doi: 10.1111/lam.13082. Epub 2018 Oct 25.
4
The Pros and Cons of the Use of Laser Ablation Synthesis for the Production of Silver Nano-Antimicrobials.使用激光烧蚀合成法制备银纳米抗菌剂的利弊。
Antibiotics (Basel). 2018 Jul 28;7(3):67. doi: 10.3390/antibiotics7030067.
5
Gold nanoparticle-mediated laser stimulation induces a complex stress response in neuronal cells.金纳米颗粒介导的激光刺激会引起神经元细胞的复杂应激反应。
Sci Rep. 2018 Apr 25;8(1):6533. doi: 10.1038/s41598-018-24908-9.
6
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Nanomaterials (Basel). 2018 Jan 30;8(2):78. doi: 10.3390/nano8020078.
7
Calculation extinction cross sections and molar attenuation coefficient of small gold nanoparticles and experimental observation of their UV-vis spectral properties.计算小金纳米粒子的消光截面和摩尔衰减系数，并实验观察其紫外-可见光谱性质。
Spectrochim Acta A Mol Biomol Spectrosc. 2018 Feb 15;191:513-520. doi: 10.1016/j.saa.2017.10.047. Epub 2017 Oct 20.
8
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Materials (Basel). 2016 May 24;9(6):406. doi: 10.3390/ma9060406.
9
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Adv Funct Mater. 2017 Jan 19;27(3). doi: 10.1002/adfm.201604213. Epub 2016 Nov 28.
10
Surface plasmon resonance in gold nanoparticles: a review.金纳米颗粒中的表面等离子体共振：综述
J Phys Condens Matter. 2017 May 24;29(20):203002. doi: 10.1088/1361-648X/aa60f3.