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石墨烯添加对复合rGO/PAN膜性能的影响及其在水消毒中的潜在应用。

The Influence of Graphene Addition on the Properties of Composite rGO/PAN Membranes and Their Potential Application for Water Disinfection.

作者信息

Fryczkowska Beata, Machnicka Alicja, Biniaś Dorota, Ślusarczyk Czesław, Fabia Janusz

机构信息

Institute of Environmental Protection and Engineering, Faculty of Materials, Civil and Environmental Engineering, University of Bielsko-Biala, Willowa 2, 43-309 Bielsko-Biala, Poland.

Institute of Textile Engineering and Polymer Materials, Faculty of Materials, Civil and Environmental Engineering, University of Bielsko-Biala, Willowa 2, 43-309 Bielsko-Biala, Poland.

出版信息

Membranes (Basel). 2020 Mar 29;10(4):58. doi: 10.3390/membranes10040058.

Abstract

The paper presents a method of obtaining composite polyacrylonitrile-based (PAN) membranes with the addition of reduced graphene oxide (rGO). The membranes were obtained using phase inversion method from a homogeneous rGO dispersion in a solution of PAN dissolved in N, N-dimethylformamide (DMF). The impact of the amount of rGO addition to the PAN matrix on the physicochemical, structural, transport, and separation properties and on fouling resistance was studied. Composite membranes, due to the method of preparation used and the addition of rGO, are characterized by very good transport properties (~390 L/m h) and by a high degree of protein retention (85%). Reduced graphene oxide has biocidal properties, which, as we have shown, depend on the size of nanoparticles and the type of microorganism. rGO/PAN membranes, on the other hand, show biostatic properties against Gram-negative bacteria (), Gram-positive bacteria () and fungi (). Thus, the obtained composite membranes can be potentially used in water disinfection.

摘要

本文介绍了一种通过添加还原氧化石墨烯(rGO)来制备复合聚丙烯腈基(PAN)膜的方法。这些膜是采用相转化法,从rGO在溶解于N,N - 二甲基甲酰胺(DMF)的PAN溶液中的均匀分散体制备而成。研究了向PAN基质中添加rGO的量对物理化学、结构、传输和分离性能以及抗污染性能的影响。由于所使用的制备方法和rGO的添加,复合膜具有非常好的传输性能(约390 L/m·h)和高蛋白质截留率(85%)。还原氧化石墨烯具有杀菌性能,正如我们所表明的,这取决于纳米颗粒的大小和微生物的类型。另一方面,rGO/PAN膜对革兰氏阴性菌()、革兰氏阳性菌()和真菌()具有抑菌性能。因此,所获得的复合膜有可能用于水消毒。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1848/7231406/fd2a6116f2e9/membranes-10-00058-g001.jpg

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